High-pressure operation through high strength linepipe reduces long distance transportation cost of natural gas. In order to maximize the cost reduction, X120 UOE pipe has been developed. Low C-Mo-B steel with fine-grained lower bainite (LB) microstructure realizes high strength, excellent low temperature toughness and good weldability. The technology was verified in small-scale commercial production or “mini-rolls”. Suitability for use as linepipe was demonstrated through an extensive development program that covers burst test, fracture toughness evaluation, girth welding technology, etc. A demonstration line was successfully constructed using the pipes manufactured in the “mini-rolls”.
We investigated the behavior of casing pipe body and connections under simulated thermal recovery conditions. The study, performed in a new computer-controlled thermal-well simulator, examined the thermal stress behavior and leak resistance of pipe and connections at temperatures up to 354°C [670°F] under severe loading conditions similar to those encountered in thermal wells. We also studied the biaxial collapse resistance of the casing under the large axial tension that would exist after the cooling period in a steam-stimulation process. Results indicate that in a steam-injection process in which the casing is maintained at its maximum temperature for a period of time, stress relaxation can occur in a constrained production casing, resulting in the development of excessive tensile stress during the cooling period. Premium connections with metal-to-metal seals maintained gas leak resistance at temperatures up to 354°C [670°F], whereas the connections without metal seals did not. The biaxial collapse resistance of casing under large axial tension depended on the stress/strain characteristics of the material. Hot-rolled Grade K55 casing with work-hardening characteristics showed a biaxial collapse resistance higher than that predicted by the von Mises yield criterion. From results of this study, we concluded that heavyweight Grade K55 casing with premium connections is a good candidate for thermal well completions.
Enantiomeric piperazin-2-one derivatives, N,N'-ethylene-bridged alanylphenylalanines (1a or 1b), were synthesized using (S)- or (R)-alanine and phenylalanine as starting materials, and were inserted into the second and third positions of enantiomeric pseudo-tetrapeptides (P1a- or P1b-OEt). The corresponding piperazine derivatives (1a- or 1b-sRed) obtained by selective BH3 reduction of the amide carbonyl groups of 1a or 1b were similarly inserted into the same positions of tetrapeptides (P1a- and P1b-sRed). Enantiomeric N,N'-ethylene-bridged tyrosyltyrosine derivatives (2a or 2b) obtained from (S)- or (R)-tyrosine were also inserted into the first and second positions of two pairs of enantiomeric tetrapeptides (P2a- and P2b-OEt or P'2a- and P'2b-OEt). The opiate activities of the eight peptides thus obtained were studied by use of the mouse vas deferens and the guinea pig ilcum assays in order to elucidate the structure-activity relationships of these peptides, especially with respect to stereochemistry.
To suppress the appearance of Lu¨ders strain and to decrease yield to tensile strength ratio in the L-direction (longitudinal direction), as well as the C-direction (circumferential direction), have been more important for strain-based design. In this study, conventional UOE and ERW pipes were examined in terms of tensile properties in both directions. In the case of UOE pipes, yield point was clearly observed on the stress-strain curve in the C-direction. However, stress-strain curves in the L-direction showed the round-house type. This difference became prominent after heat treatment for the anti-corrosion. Namely, clear Lu¨ders strain appeared in the C-direction at a lower aging temperature compared with that in the L-direction. On the other hand, contrasting results were obtained in the case for ERW pipes. Thus far, it’s been thought that the difference between UOE and ERW pipe was caused by the direction of final strain during the pipe forming process. There are also differences in the occurrence of Lu¨ders strain between each grade. A stress-strain curve maintained the round-house type in X100 grade pipe after the heat treatment at 240°C for five minutes; however, X70 grade pipe showed the stress-strain curve in the L-direction with Lu¨ders strain after the heat treatment at the same temperature.
In strain-based design, the overmatch condition in the girth weld portion primarily must be maintained. The pipes may also be required to have a low yield to tensile (Y/T) ratio and a high uniform elongation (U.EL) in the longitudinal direction to achieve a high compressive buckling strain. However, change in the mechanical properties by heating during coating treatment has not been paid attention so much. Furthermore, how much the mechanical properties change is affected by production conditions is unclear. This study aims to clarify firstly the relation between the mechanical properties (Y/T ratio, U.EL etc.) and the microstructure and secondly the change in mechanical properties by thermal coating treatment. The Y/T ratio and U.EL are affected by the volume fraction of ferrite and the secondary phase, which are changed by thermomechanical control processing (TMCP) conditions. For example, use of dual phase microstructure is very effective for decreasing the Y/T ratio and increasing the U.EL as the pipe. On the other hand, yield strength (YS) rises and the U.EL does not change after coating. The increase in the YS after coating is influenced by the microstructure and TMCP conditions. Resultantly, dependence of the Y/T ratio on the microstructure and TMCP conditions is reduced for line pipes after thermal coating treatment.
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