No abstract

No abstract

Converting ethylene to biojet fuel range hydrocarbons via oligomerization is an important step in biojet production from ethanol. The present study investigates the catalytic ethylene oligomerization over platelet Ni-AlSBA-15 mesoporous catalysts. The catalysts are synthesized and characterized using nitrogen adsorption-desorption isotherms, X-ray fluorescence and X-ray diffraction techniques. The catalytic performances are then evaluated in a continuous flow fixed-bed reactor under various conditions of reaction weight hourly space velocities (0.56-4.5 h −1), temperatures (150-350 °C) and pressures (1-20 bar). Experimental results demonstrate that platelet Ni-AlSBA-15 is a promising catalyst for the ethylene oligomerization to produce biojet fuel range hydrocarbons. It performs a good catalytic activity, yielding 98-99 mol% ethylene conversion and 34-42 wt% C 8+ selectivity at 0.56 h −1 , 275-300 °C and 20 bar. The obtained products contain mainly C 4-C 10 olefins with low aromatic compounds. Moreover, the catalyst exhibits good stability of the activity during long periods of operation.

No abstract

No abstract