Four-dimensional (4D) active shape-changing structures based on shape memory polymers (SMPs) and shape memory nanocomposites (SMNCs) are able to be controlled in both space and time and have attracted increasing attention worldwide. However, conventional processing approaches have restricted the design space of such smart structures. Herein, 4D active shape-changing architectures in custom-defined geometries exhibiting thermally and remotely actuated behaviors are achieved by direct-write printing of ultraviolet (UV) cross-linking poly(lactic acid)-based inks. The results reveal that, by the introduction of a UV cross-linking agent, the printed objects present excellent shape memory behavior, which enables three-dimensional (3D)-one-dimensional (1D)-3D, 3D-two-dimensional (2D)-3D, and 3D-3D-3D configuration transformations. More importantly, the addition of iron oxide successfully integrates 4D shape-changing objects with fast remotely actuated and magnetically guidable properties. This research realizes the printing of both SMPs and SMNCs, which present an effective strategy to design 4D active shape-changing architectures with multifunctional properties. This paves the way for the further development of 4D printing, soft robotics, flexible electronics, minimally invasive medicine, etc.
Lightweight, flexibility, and low thickness are urgent requirements for next-generation high-performance electromagnetic interference (EMI) shielding materials for catering to the demand for smart and wearable electronic devices. Although several efforts have focused on constructing porous and flexible conductive films or aerogels, few studies have achieved a balance in terms of density, thickness, flexibility, and EMI shielding effectiveness (SE). Herein, an ultrathin, lightweight, and flexible carbon nanotube (CNT) buckypaper enhanced using MXenes (Ti3C2Tx) for high-performance EMI shielding is synthesized through a facile electrophoretic deposition process. The obtained Ti3C2Tx@CNT hybrid buckypaper exhibits an outstanding EMI SE of 60.5 dB in the X-band at 100 μm. The hybrid buckypaper with an MXene content of 49.4 wt% exhibits an EMI SE of 50.4 dB in the X-band with a thickness of only 15 μm, which is 105% higher than that of pristine CNT buckypaper. Furthermore, an average specific SE value of 5.7 × 104 dB cm2 g−1 is exhibited in the 5-μm hybrid buckypaper. Thus, this assembly process proves promising for the construction of ultrathin, flexible, and high-performance EMI shielding films for application in electronic devices and wireless communications.
Human bones have unique structure and characteristics, and replacing a natural bone in the case of bone fracture or bone diseases is a very complicated problem.
PurposeThe purpose of this paper is to examine the underlying mechanism and physico‐chemical requirements of chemo‐responsive shape change/memory polymers and to explore the future trend of development and potential applications.Design/methodology/approachWorking mechanism in chemo‐responsive shape change/memory polymers is firstly identified. And then the physico‐chemical requirements for the representative polymers are characterized.FindingsThe different working mechanisms, fundamentals, physico‐chemical requirements and theoretical origins have been discussed. Current research and development on the fabrication strategies of chemo‐responsive shape change/memory polymers have been summarised. The future trend and potential applications have been explored and estimated.Research limitations/implicationsThis review examines physico‐chemical requirements and theoretical origins necessary to achieve chemo‐responsiveness, and then discusses recent developments and future trends.Practical implicationsShape change/memory polymers can be used in the broad field of bio‐ and/or medicine.Originality/valueBreakthroughs and rapid development of chemo‐responsive shape change/memory polymers will significantly improve the research and development of smart materials, structures and systems.
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