An effective strategy to significantly boost the capacitive properties of Fe2O3‐based anodes by Ti doping and poly(3,4‐ethylenedioxythiophene) (PEDOT) coating is successfully demonstrated. The Ti‐Fe2O3@PEDOT electrode exhibits a significant capacitance improvement and exceptionally cyclic stability. A remarkable energy density of 0.89 mWh cm−3 can be obtained for a high‐performance asymmetric supercapacitor device consisting of Ti‐Fe2O3@PEDOT and a MnO2 anode.
A novel end-on azide-bridged homospin 1D chain, Co(bt)(N3)2 (1) (bt = 2,2'-bithiazoline), is constructed by sharing edges of Co(II) distorted octahedrons to form a helix, which shows magnetic hysteresis with steps and slow relaxation below 5-6 K, typical of single-chain magnet behavior.
Pelitic schists from Qingshuigou in the Northern Qilian Mountains of China contain mainly glaucophane, garnet, white mica, clinozoisite, chlorite and piemontite. Isotopic age dating of these schists provides new constraints on the formation of the highgrade blueschists at Qingshuigou. White mica 40 Ar/ 39 Ar ages range from 442.1 to 447.5 Ma (total fusion age of single grain) and from 445.7 to 453.9 Ma (integrated age of white mica concentrates). These ages (442.1-453.9 Ma) represent the peak metamorphic ages or cooling ages of the blueschists during exhumation shortly after peak metamorphism. The 40 Ar/ 39 Ar dates in the present study are similar to ages previously reported for eclogites and blueschists in the area; this suggests that both the eclogites and pelitic sediments underwent high-grade metamorphism during the same subduction event. From this chronological evidence and the presence of well-developed Silurian remnant-sea flysch and Devonian molasse, it is concluded that the Northern Qilian Ocean had closed by the end of the Ordovician, and rapid orogenic uplift followed in the Devonian.
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