A novel approach for rhodium(iii)-catalyzed C–H functionalization of 2,2′-bipyridine derivatives was developed, which elucidated significant substituent effects on the rollover cyclometalation.
We report the first silver-promoted imino-phosphorylation of γ,δ-unsaturated oxime esters with P(O)H compounds to synthesize various phosphorylated pyrrolines.
We reported the first palladium‐catalyzed copper‐free cascade cyclization/alkynylation of alkene‐tethered carbamoyl chlorides with terminal alkynes, which provided an alternative approach to synthesize various functionalized oxindoles bearing a propargyl all‐carbon quaternary center. This protocol was highly efficient and exhibited good functional group compatibility, as well as the broad substrate scope.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.