HIGHLIGHTS Low LCOE is achieved due to extreme low cost of perovskites in tandem PVs Further improving tandem module lifetime and efficiency reduces LCOE LCOE decrease rates are used to measure the research efforts
Loading ReS2 nanosheets (NSs) on planar p-type doping Si substrate has been proved that it can work well in photoelectrochemical (PEC) water splitting for hydrogen evolution reaction (HER). High PEC...
To
improve PEC water splitting efficiency, Cu2O thin
film electrodeposites on pyramidal Si (PSi) was innovatively introduced
as an antireflective substrate combining with an Au layer. In this
way, a PSi/Au/Cu2O photocathode exhibits a photocurrent
enhanced 330% more than that of bare planar Si/Au/Cu2O
photocathode. Compared with reversible hydrogen electrode the final
fabricated photocathode with earth-abundant NiCo-LDH semiconductor
cocatalyst exhibits a highly competitive photocurrent of 7.54 mA cm–2 at 0 V. It mainly results from the improved light
trapping, enhanced carrier separation, and NiCo-LDH with triple enhanced
effects. That means p-Cu2O and NiCo-LDH possess a type-II
heterojunction to enhance photocarrier separation efficiency. Ultimately,
NiCo-LDH semiconductor cocatalyst also acts as a maskant which can
enhance PSi/Au/Cu2O photocathode stability. Through light
trapping effect of the pyramidal Si structure and type-II heterojunction
for efficient charge separation, this work provide insight into superior
performance in PEC water splitting.
The heterostructuring and doping concepts have proved to obtain a novel n-InGaN/p-Cu2O nanowire (NW) photoanode by strong enhancement of the photocurrent compared to a bare InGaN NW photoanode in solar water splitting. The large photocurrent is due to the maximized photocarrier separation and hole transfer to the surface in the depletion zone of the p–n heterojunction established by the p-Cu2O layer, forming a thin, uniform shell-layer around the n-InGaN NW core by electrodeposition. For sufficiently thin Cu2O layers, the upward energy band bending in the depletion zone extends up to the surface for optimized hole transport and surface reaction. Thick Cu2O layers on top of the InGaN NWs act as common photocathodes. The functional InGaN/Cu2O heterostructure core-shell NW photoanode is chemically self-stabilized at positive applied voltage by a thin CuO surface layer. Final deposition of the earth-abundant NiOOH co-catalyst boosts the photocurrent of the InGaN/Cu2O/NiOOH complete NW photoanode into the competitive mA/cm2 range.
A one-compartment H 2 O 2 photofuel cell (PFC) with a photoanode based on InGaN nanowires (NWs) is introduced for the first time. The electrocatalytic and photoelectrocatalytic properties of the InGaN NWs are studied in detail by cyclic voltammetry, current versus time measurements, photovoltage measurements, and electrochemical impedance spectroscopy. In parallel, IrO x (OH) y as the co-catalyst on the InGaN NWs is evaluated to boost the catalytic activity in the dark and light. For the PFC, Ag is the best as the cathode among Ag, Pt, and glassy carbon. The PFC operates in the dark as a conventional fuel cell (FC) and under illumination with 25% increased electrical power generation at room temperature. Such dual operation is unique, combining FC and PFC technologies for the most flexible use.
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