Lattice vibrations of highly a-axis oriented CoFe 2 O 4 (CFO) films have been investigated by Raman scattering in the temperature range of 80-873 K. The five phonon modes T 1g (2), T 1g (3), E g , A 1g (1), A 1g (2), and their evolutions can be uniquely distinguished. It was found that an electron transfer between Co 2þ and Fe 3þ cations occurs in octahedral sites at about 173 K. The structure disorder in the CFO films appears with increasing the temperature, which indicates the cation migration between tetrahedral and octahedral sites. The phenomena suggest the structural transformation trend from inverse spinel to normal spinel at the elevated temperatures. V
The rotational states of an adsorbed dipole molecule in an external electric field were investigated. The surface hindering potential was modeled as a finite conical well and a dipole-field interaction was added to the hindering potential. The molecular wave functions were expressed in terms of the eigenfunctions of molecular hindered rotation in the absence of electric field. Eigenenergies were determined by the matrix diagonalization procedures. Our results showed that, for both vertically and horizontally adsorbed molecules, there is avoided crossing between two adjacent rotational energy levels, as the field strength is increased, and finally all state energies decrease rapidly as the field strength is strong enough. The avoided crossing is due to the redistribution of wave function between different potential well regions. By employing the sudden unhindrance approximation, the rotational-state distributions of molecules desorbing from a solid surface in the presence of external electric field were calculated. Our results showed that the rotational-state distributions are significantly influenced by the external electric field. Since the electric field increases the ground-state energy of adsorbed molecule, the distribution shifts towards the high-J region if the electric field is applied to orient the molecular axis against the molecular preferred orientation. On the contrary, the distribution shifts towards the low-J region if the electric field is applied to orient the molecular axis towards molecular preferred orientation because the electric field decreases the ground-state energy of adsorbed molecule. The solutions to the finite conical well were also used to calculate the rotational alignment in the photodesorption of CO from Cr 2 O 3 (0001). Our results showed that at low-J values the CO molecules desorb like a helicopter, while at high-J values a cartwheel-like motion is preferred. This result is in qualitative agreement with the experimental observation.
Placing a quantum dot close to a metal nanowire leads to drastic changes in its radiative decay behavior because of evanescent couplings to surface plasmons. We show how two non-Markovian effects, band-edge and retardation, could be observed in such a system. Combined with a quantum dot p-i-n junction, these effects could be readout via current-noise measurements. We also discuss how these effects can occur in similar systems with restricted geometries, like phononic cavities and photonic crystal waveguides. This work links two previously separate topics: surface-plasmons and current-noise measurements.
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