Semiconducting metal oxide-based nanowires (SMO-NWs) for gas sensors have been extensively studied for their extraordinary surface-to-volume ratio, high chemical and thermal stabilities, high sensitivity, and unique electronic, photonic and mechanical properties. In addition to improving the sensor response, vast developments have recently focused on the fundamental sensing mechanism, low power consumption, as well as novel applications. Herein, this review provides a state-of-art overview of electrically transduced gas sensors based on SMO-NWs. We first discuss the advanced synthesis and assembly techniques for high-quality SMO-NWs, the detailed sensor architectures, as well as the important gas-sensing performance. Relationships between the NWs structure and gas sensing performance are established by understanding general sensitization models related to size and shape, crystal defect, doped and loaded additive, and contact parameters. Moreover, major strategies for low-power gas sensors are proposed, including integrating NWs into microhotplates, self-heating operation, and designing room-temperature gas sensors. Emerging application areas of SMO-NWs-based gas sensors in disease diagnosis, environmental engineering, safety and security, flexible and wearable technology have also been studied. In the end, some insights into new challenges and future prospects for commercialization are highlighted.
Low-dimensional semiconductors have been considered excellent materials to construct photodetectors for infrared detection with an easy process and excellent compatibility but suffer from low detectivity mainly owing to the poor light absorption of the ultra-thin body. Here, we demonstrate a thin film transistor (TFT) based short-wave infrared photodetector consisting of a carbon nanotube (CNT) TFT gated by a PbS colloidal quantum dots (CQDs) based heterojunction. The thick PbS CQDs' film efficiently absorbs infrared light and then excites and separates electron–hole pairs to generate a photovoltage at the pn heterojunction of the PbS CQDs/ZnO film. The photovoltage is further amplified and transduced in situ by the CNT TFT under the heterojunction, and then the detector featured a specific detectivity of 5.6 × 1013 Jones under 1300 nm illumination and a fast response of the sub-ms level (0.57 ms). The CQDs based heterojunction gating TFT represents a universal architecture for highly sensitive low-dimensional semiconductor based infrared photodetectors, competitive with state-of-the-art epitaxial semiconductors and enabling monolithic integration technology.
A unique positive-to-negative transition of temperature coefficient of conductance (TCC) was observed in self-assembled close-packed Au nanoparticle (AuNP) arrays. The transition of TCC can be interpreted properly with a diffusive hopping model, in which the Coulomb charging energy E a plays a significant role. Two parameters of AuNP arrays, the nearest neighboring number and the particle core size, have been varied to tune E a . Our data show that the positive-to-negative transitions of TCC are relevant to both parameters, which confirms the validity of the diffusive hopping model. V C 2014 AIP Publishing LLC. [http://dx.
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