Low-sensitivity and high-energy explosives (LSHEs) are highly desired for their comprehensive superiority of safety and energy. Crystal packing is crucial to both the safety and energy, and therefore becomes of interest in energetic crystal engineering. This work carries out systemic analyses on the crystal packing of 11 existing LSHEs with both energy and safety close or superior to TNT. As a result, we find that the LSHE crystals wholly feature π−π stacking with the aid of intermolecular hydrogen bonding. Each LSHE molecule is πbonded with a big conjugated structure composed of all nonhydrogen atoms in the entire molecule. Intramolecular hydrogen bonding exists in most LSHE molecules with strongly active hydrogen bond (HB) donors of amino and hydroxyl groups, and various strength. These big π-conjugated structures and intramolecular HBs lead to planar molecules with high stability, settling a base of π−π stacking in crystals. With the help of intermolecular HBs, the π−π stacking holding the LSHE crystals appears in four modes. Among them, the face-to-face stacking (always offset) gives rationally the smallest steric hindrance when interlayer slide occurs in crystal, which is the reason for very low impact sensitivity. This work suggests that the planar conjugated molecular structure and intermolecular hydrogen bonding supporting the π−π stacking are necessary to the crystal engineering of LSHEs.
Molecular and crystal designs are crucial to the engineering of high-energy explosives, which are a class of substantial materials usually with high costs and high risks.Understanding their structures, properties, and performances, and the relationships among them is the basis for the design. As a continuation of a systemic analysis of the crystal packing of low-sensitivity and high-energy explosives (LSHEs) (Cryst. Growth Des. 2014, 14, 4703−4713), we present in this work another analysis of 10 existing impact-sensitive high-energy explosives (SHEs), which possess both velocities of detonation and impact sensitivity close to or higher than those of RDX. We find that SHE molecules are usually less stable than LSHE ones, due to the deficiencies of big π-conjugated molecular structures, and adequate and strong intramolecular hydrogen bonds (HBs) even though H atoms are contained. The intermolecular HBs cannot be formed sometimes in H-contained SHE crystals, and the noncovalent O•••O interactions dominate the connection of SHE molecules to build a three-dimensional network and hold crystals, generally, with the strength above intermolecular HBs. The absence of single-atom-layered stacking in SHE crystals makes the intermolecular sliding difficult or even unallowed when against impact, which leads to inefficiency of energy buffering and ease of molecular decay, hot spot formation, and final combustion or detonation. In contrast to LSHEs, SHEs are disadvantageous on dual structural levels causing their high sensitivity: molecules with low stability and crystals without HB-aided single-atom-layered stacking. It re-verifies that the intermolecular HB-aided π−π stacking is necessary for crystal engineering of LSHEs, which are highly desired currently.
Optical metasurfaces have shown unprecedented capabilities in the local manipulation of the light's phase, intensity, and polarization profiles, and represent a new viable technology for applications such as high-density optical storage, holography and display. Here, a novel metasurface platform is demonstrated for simultaneously encoding color and intensity information into the wavelength-dependent polarization profile of a light beam. Unlike typical metasurface devices in which images are encoded by phase or amplitude modulation, the color image here is multiplexed into several sets of polarization profiles, each corresponding to a distinct color, which further allows polarization modulation-induced additive color mixing. This unique approach features the combination of wavelength selectivity and arbitrary polarization control down to a single subwavelength pixel level. The encoding approach for polarization and color may open a new avenue for novel, effective color display elements with fine control over both brightness and contrast, and may have significant impact for high-density data storage, information security, and anticounterfeiting.
Benefiting from the unprecedented capability of metasurfaces in the manipulation of light propagation, metalenses can provide novel functions that are very challenging or impossible to achieve with conventional lenses. Here, an approach to realizing multi‐foci metalenses is proposed and experimentally demonstrated with polarization‐rotated focal points based on geometric metasurfaces. Multi‐foci metalenses with various polarization rotation directions are developed using silicon pillars with spatially variant orientations. The focusing characteristic and longitudinal polarization‐dependent imaging capability are demonstrated upon the illumination of a linearly polarized light beam. The uniqueness of this multi‐foci metalens with polarization‐rotated focal points may open a new avenue for imaging, sensing, and information processing.
With the non-ionizing, non-invasive, high penetration, high resolution and spectral fingerprinting features of terahertz (THz) wave, THz spectroscopy has great potential for the qualitative and quantitative identification of key substances in biomedical field, such as the early diagnosis of cancer, the accurate boundary determination of pathological tissue and non-destructive detection of superficial tissue. However, biological samples usually contain various of substances (such as water, proteins, fat and fiber), resulting in the signal-to-noise ratio (SNR) for the absorption peaks of target substances are very small and then the target substances are hard to be identified. Here, we present recent works for the SNR improvement of THz signal. These works include the usage of attenuated total reflection (ATR) spectroscopy, the fabrication of sample-sensitive metamaterials, the utilization of different agents (including contrast agents, optical clearing agents and aptamers), the application of reconstruction algorithms and the optimization of THz spectroscopy system. These methods have been proven to be effective theoretically, but only few of them have been applied into actual usage. We also analyze the reasons and summarize the advantages and disadvantages of each method. At last, we present the prospective application of THz spectroscopy in biomedical field.
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