A polymer‐based magnesium (Mg) electrolyte is vital for boosting the development of high‐safety and flexible Mg batteries by virtue of its enormous advantages, such as significantly improved safety, potentially high energy density, ease of fabrication, and structural flexibility. Herein, a novel polytetrahydrofuran‐borate‐based gel polymer electrolyte coupling with glass fiber is synthesized via an in situ crosslinking reaction of magnesium borohydride [Mg(BH4)2] and hydroxyl‐terminated polytetrahydrofuran. This gel polymer electrolyte exhibits reversible Mg plating/stripping performance, high Mg‐ion conductivity, and remarkable Mg‐ion transfer number. The Mo6S8/Mg batteries assembled with this gel polymer electrolyte not only work well at wide temperature range (−20 to 60 °C) but also display unprecedented improvements in safety issues without suffering from internal short‐circuit failure even after a cutting test. This in situ crosslinking approach toward exploiting the Mg‐polymer electrolyte provides a promising strategy for achieving large‐scale application of Mg‐metal batteries.
Rechargeable
magnesium (Mg) metal batteries are provided with potential
advantages over lithium counterparts with respect to volumetric capacity
and natural abundance (equivalent to low cost and sustainability).
However, Mg metal anodes suffer from surface passivating behavior
among numerous conventional Mg electrolytes, leading to irreversible
Mg plating/stripping behavior. Herein, a modified Mg metal anode with
a bismuth (Bi)-based artificial protective layer has been obtained
via a facile solution process (soaking briefly in bismuth trichloride
solution). This Bi-based protective layer is mainly composed of ion-conducting
Bi metal and corresponding alloy and electronically insulating magnesium
chloride. Various electrochemical tests and interface characterizations
have proved that the protected Mg electrodes effectively inhibit the
harmful parasitic reaction between Mg metal and noncorrosive Mg electrolyte,
which further enables suppression of uneven growth during repeated
Mg stripping/plating. More importantly, the assembled Mg–Cu2–x
S and Mg–O2 full
batteries utilizing the as-modified Mg anodes all deliver remarkably
improved performance owing to the superior protection properties of
a Bi-based artificial layer. These novel findings will inspire lot
of efforts to modify the Mg metal anode with targeted surface coatings
for high-performance rechargeable Mg batteries.
Tungsten oxynitride nanowires were generated by the reaction of ammonia with ultra-thin tungsten oxide nanowires which were themselves prepared by a simple solvo-thermal treatment of tungsten chloride in a cyclohexanol solvent. The resulting tungsten oxynitride nanowires exhibited a high specific surface area of 221 m 2 g 21 , even exceeding that of 151 m 2 g 21 for the bundled and ultra-thin tungsten oxide nanowire precursor. The observed weak, temperature-independent paramagnetism indicates that the tungsten oxynitride nanowires are metallic, but no superconducting transition was observed above 2 K.
Low-temperature magnetic properties of hematite nanorods, prepared by both iron−water vapor reactions
(sample 1) and hydrothermal methods (sample 2), were studied by superconducting quantum interference
device (SQUID) magnetometry. The Morin transition temperature was found to be 122 K in hematite
nanorod sample 1, and an unexpected phenomenon was found under an applied field of 10 Oe. These
nanorods (sample 1) show an abrupt decrease of the magnetic susceptibility at ca. 122 K, contrary to the
abrupt increase normally attributed to the Morin transition in bulk hematite. The origin of this phenomenon
can be traced to the probable coherence of the one-dimensional shape anisotropy with the magnetocrystalline anisotropy. In contrast, no obvious Morin transition was found in hematite nanorod sample 2.
Ultra-thin W(18)O(49) nanowires were initially obtained by a simple solvothermal method using tungsten chloride and cyclohexanol as precursors. Thermal processing of the resulting bundled nanowires has been carried out in air in a tube furnace. The morphology and phase transformation behavior of the as-synthesized nanowires as a function of annealing temperature have been characterized by x-ray diffraction and electron microscopy. The nanostructured bundles underwent a series of morphological evolution with increased annealing temperature, becoming straighter, larger in diameter, and smaller in aspect ratio, eventually becoming irregular particles with size up to 5 µm. At 500 °C, the monoclinic W(18)O(49) was completely transformed to monoclinic WO(3) phase, which remains stable at high processing temperature. After thermal processing at 400 °C and 450 °C, the specific surface areas of the resulting nanowires dropped to 110 m(2) g(-1) and 66 m(2) g(-1) respectively, compared with that of 151 m(2) g(-1) for the as-prepared sample. This study may shed light on the understanding of the geometrical and structural evolution occurring in nanowires whose working environment may involve severe temperature variations.
Supporting InformationFig. S1 In-situ TEM observation of the FeWO 4 flowers turning under electron beam. (a-b) show the 6-folded feature of a flower when initially exposed to electron beam during observation and tilting of the sample holder. (c-i) revealed a series of turning sequences of the same flower, after exposing to the focused electron beam for about 10 min. When shifting the beam towards the flower, it started to turn over, projecting a platelet shape at some stage, images (c) and (i). Damage on the surface was also observed due to the irradiation of the high density electron beam (TEM operated at 200 KeV). Pictures from (c-i) were taken at an interval about 40 s. The scale bar in the images is same.
Four kinds of CNTs with different morphologies were produced by chemical vapour deposition method. After oxidation with nitric acid, their specific surface area, particle size distribution and functional groups on the surfaces were characterized. Adsorption isothermal experiment shows that the CNTs with more defects, which can be easily introduced more functional groups on their surfaces prepared at 650 -C, have higher lead adsorption capability from aqueous solution and are promising adsorbents in wastewater treatment. D
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.