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A highly luminescent LnMOF {[Eu 2 (bqdc) 3 (H 2 O)(DMF) 3 ]$0.5DMF$H 2 O} n (1, bqdc ¼ 2,2 0 -biquinoline-4,4 0dicarboxylate) was designed and synthesized. It was characterized by single crystal X-ray diffraction, PXRD, TGA, EA and FT-IR. A new strategy for preparing mechanically robust MOF thin films was developed by electrodeposition in combination with subsequent solvothermal synthesis. A portable sensor device prototype consisting of a film of 1 was conveniently fabricated by using this new strategy and this sensor device exhibits a highly selective response to Hg 2+ . Its luminescence quenching can be distinguished clearly with the naked eye when illuminated by a handy UV banknote detector. The diffusion kinetics of Hg 2+ into the LnMOF film is first proposed.

Up to date, no consensus has been achieved regarding the possibility of detecting neuronal currents by MRI (ncMRI) in human brain. To evaluate the detectability of ncMRI, an effective way is to simulate ncMRI signal with the realistic neuronal geometry and electrophysiological processes. Unfortunately, previous realistic ncMRI models are based on rat and monkey neurons. The species difference in neuronal morphology and physiology would prevent these models from simulating the ncMRI signal accurately in human subjects. The aim of this study is to bridge this gap by establishing a realistic ncMRI model specifically for human cerebral cortex. In this model, the ncMRI signal was simulated using anatomically reconstructed human pyramidal neurons and their biophysical properties. The modeling results showed that the amplitude of ncMRI signal significantly depends on the density of synchronously firing neurons and imaging conditions such as position of imaging voxel, direction of main magnetic field (B 0 ) relative to the cortical surface and echo time. The results indicated that physiologically-evoked ncMRI signal is too weak to be detected (magnitude/phase change 21.4 3 10 26 /0.02°), but the phase signal induced by spontaneous activity may reach a detectable level (up to 0

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This study investigated the polycyclic aromatic hydrocarbon (PAH) pollution in the reconstructed land of an abandoned industrial site: a coking plant in Beijing. To meet the needs of urban development, many factories have had to be relocated from city centers, and abandoned industrial sites often need to be transformed into residential land or urban green space through a series of restoration measures. It is necessary to study the level of residual pollutants and potential risks associated with industrial reconstructed land. The concentration of 16 PAHs in the study area ranged from 314.7 to 1618.3 µg/kg, and the average concentration was still at a medium pollution level; the concentration of PAHs in the original coking workshop had the highest levels (1350.5 µg/kg). The PAHs in the soil were mainly low-ring aromatics, especially naphthalene and phenanthrene. The isomer method and principal component analysis indicated that PAHs in the topsoil were the result of coal and biomass combustion. The seven carcinogenic PAHs were the main contributors to the total toxicity equivalence. The genetic toxicity of benzo[a]pyrene was relatively low, and the results were related to the concentration level. There were potential carcinogenic risks for people of varying ages in this residential area. In total, gender differences were small, and the comprehensive lifetime cancer risk level was still acceptable. For the remaining plots at the study site, the daily intake of PAHs by construction workers was between 0.74–2.31 ng/kg bw/day, which requires further evaluation about ignored area occupational exposure to environmental pollutants.

The solar radiation or insolation at a specific locality on the Earth's surface is determined by the distance of this point from the sun and by the angle with which the radiation hits the earth's surface. The theory that variations in the earth's orbit determine the amount of radiation and therefore the climate which is the Milankovitch Cycle. In non‐marine lacustrine rift basin, the changes of climate can be recorded by the palaeontology, and it also plays an important role in controlling lacustrine fluctuations. The lacustrine fluctuations are indicated by coastal onlap, which is the landward or lake‐ward onlap of non‐marine coastal deposits. In this paper, based on borehole data, wireline logs, seismic datasets, biostratigraphic data and palaeontology, the lacustrine fluctuation curve can be reconstructed from the onlap of lacustrine deposits in non‐marine sequences. The durations and magnitudes of these changes can be used to construct charts showing cycles of the relative rising and falling of lake level. In addition, the changes of lake level can also be reflected by the palaeontology such as pollen. The living conditions and distributions of pollen can be a good indicator for climate changes and lacustrine fluctuations in an a non‐marine setting. The calculation of the Milankovitch Cycle can be determined by the GR log in the study area which keeps a record of cycle changes. All climatic changes and lacustrine fluctuations are mainly resulted from the Milankovitch Cycles, and therefore, through the reconstruction of lacustrine fluctuations, climate changes and the Milankovitch Cycle, the correspondences among them can be clearly addressed. All the results can contribute a lot in theory research in the study area and lead to a new focus in practical hydrocarbon exploration and exploitation.

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Cellulosimicrobium cellulans CWS2, a novel strain capable of utilizing benzo(a)pyrene (BaP) as the sole carbon and energy source under nitrate-reducing conditions, was isolated from PAH-contaminated soil. Temperature and pH significantly affected BaP biodegradation, and the strain exhibited enhanced biodegradation ability at temperatures above 30 °C and between pH 7 and 10. The highest BaP removal rate (78.8%) was observed in 13 days when the initial BaP concentration was 10 mg/L, and the strain degraded BaP at constant rate even at a higher concentration (50 mg/L). Metal exposure experimental results illustrated that Cd(II) was the only metal ion that significantly inhibited biodegradation of BaP. The addition of 0.5 and 1.0 g/L glucose enhanced BaP biodegradation, while the addition of low-molecular-weight organic acids with stronger acidity reduced BaP removal rates during co-metabolic biodegradation. The addition of phenanthrene and pyrene, which were degraded to some extent by the strain, showed no distinct effect on BaP biodegradation. Gas chromatography–mass spectrometry (GC-MS) analysis revealed that the five rings of BaP opened, producing compounds with one to four rings which were more bioavailable. Thus, the strain exhibited strong BaP degradation capability and has great potential in the remediation of BaP-/PAH-contaminated environments.