Collective effects on thermophoresis of aqueous particle suspensions are studied experimentally and theoretically. A microfluidic device is used to characterize thermophoretic transport of 100 nm, 500 nm and 1 mm particles of various concentrations in deionized (DI) water. Our experimental findings show two interesting collective effects on the Soret coefficient of colloids: (i) for smaller particles (e.g., 100 nm and 500 nm), a sign change of the Soret coefficient is observed when increasing the particle concentration; (ii) for larger particles (e.g., 1 mm), a negative Soret coefficient is always seen. A model is derived to account for the collective effect on the thermophoresis of colloids using the well-known Derjaguin-Landau-Verwey-Overbeek (DLVO) theory that combines the van der Waals (VDW) attraction and the electric double layer (EDL) repulsion. Such DLVO interactions in an inhomogeneous particle suspension can exert an additional force on particles and thus modify the mass transport of particles under both temperature and concentration gradients and also alter the corresponding Soret coefficient.It is found that the proposed theoretical model can favorably explain our experimental observations.

Thermophoresis refers to the motion of particles under a temperature gradient and it is one of the particle manipulation techniques. Regarding the thermophoresis of particles in liquid media, however, many open questions still remain, especially the role of the interfacial effect. This work reports on a systematic experimental investigation of surfactant effects, especially the induced interfacial effect, on the thermophoresis of colloids in aqueous solutions via a microfluidic approach. Two kinds of commonly used surfactants, sodium dodecyl sulfate (SDS) and cetyltrimethylammonium bromide (CTAB), are selected and the results show that from relatively large concentrations, the two surfactants can greatly enhance the thermophilic mobilities. Specifically, it is found that the colloid-water interfaces modified with more polar end groups can potentially lead to a stronger thermophilic tendency. Due to the complex effects of surfactants, further theoretical model development is needed to quantitatively describe the dependence of thermophoresis on the interface characteristics.

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Due to the large lateral area of the trailer and variable road conditions, the handling stability of a heavy tractor semi-trailer under crosswind is very important for road safety. In this present work, numerical simulation is performed to study the crosswind effects on handling stability of a tractor semi-trailer. The aerodynamic characteristics of the tractor semi-trailer under different crosswind were computed by computational fluid dynamics (CFD). Then, mathematical models to reveal the relationship between the aerodynamic forces and crosswind were constructed to serve as inputs of the multi-body dynamics to analyze the handling stability under crosswind. The performance of crosswind stability is evaluated by the response of lateral acceleration, yaw rate and the lateral displacement. The lateral acceleration and yaw rate were decreased by a maximum of 14.6% and 16.5% compared to the truck without the deflector, which showed that the crosswind aerodynamics and stability were obviously improved.

Thermophoresis of charged colloids in aqueous media has wide applications in biology. Most existing studies of thermophoresis focused on spherical particles, but biological compounds are usually non-spherical. The present paper reports a numerical analysis of the thermophoresis of a charged spheroidal colloid in aqueous media. The model accounts for the strongly coupled temperature field, the flow field, the electric potential field, and the ion concentration field. Numerical simulations revealed that prolate spheroids move faster than spherical particles, and oblate spheroids move slower than spherical particles. For the arbitrary electric double layer (EDL) thickness, the thermodiffusion coefficient of prolate (oblate) spheroids increases (decreases) with the increasing particle’s dimension ratio between the major and minor semiaxes. For the extremely thin EDL case, the hydrodynamic effect is significant, and the thermodiffusion coefficient for prolate (oblate) spheroids converges to a fixed value with the increasing particle’s dimension ratio. For the extremely thick EDL case, the particle curvature’s effect also becomes important, and the increasing (decreasing) rate of thermodiffusion coefficient for prolate (oblate) spheroids is reduced slightly.

Multiphase droplet-based and continuous liquid-liquid extraction (LLE) of phenol from oil is studied in a low width-to-height aspect ratio polymethylmethacrylate (PMMA)-based microchannel reactor. The extraction efficiency of phenol from the dispersed phase consisting of silicone oil to the external continuous water phase is studied as a function of the flow rate ratio of the two immiscible phases. This paper demonstrates that for enhancing the extraction efficiency of phenol from silicone oil to water in droplet-based microfluidic reactors, a low flow rate ratio of the external continuous phase, Q c , to dispersed oil phase, Q d , is preferable.