Determining the seismic fracture energy during an earthquake and understanding the associated creation and development of a fault zone requires a combination of both seismological and geological field data. The actual thickness of the zone that slips during the rupture of a large earthquake is not known and is a key seismological parameter in understanding energy dissipation, rupture processes and seismic efficiency. The 1999 magnitude-7.7 earthquake in Chi-Chi, Taiwan, produced large slip (8 to 10 metres) at or near the surface, which is accessible to borehole drilling and provides a rare opportunity to sample a fault that had large slip in a recent earthquake. Here we present the retrieved cores from the Taiwan Chelungpu-fault Drilling Project and identify the main slip zone associated with the Chi-Chi earthquake. The surface fracture energy estimated from grain sizes in the gouge zone of the fault sample was directly compared to the seismic fracture energy determined from near-field seismic data. From the comparison, the contribution of gouge surface energy to the earthquake breakdown work is quantified to be 6 per cent.
Cubic, rhombic dodecahedral, octahedral, and corner-truncated octahedral gold nanocrystals with sizes of tens of nanometers have been used as building blocks to form micrometer-sized supercrystals by slowly evaporating a water droplet on a substrate placed in a moist environment. Drying the droplet at 90 °C was found to yield the best supercrystals. Supercrystals were evenly distributed throughout the entire substrate surface originally covered by the droplet. Diverse supercrystal morphologies have been observed. Nanocubes formed roughly cubic supercrystals. Rhombic dodecahedra were assembled into truncated triangular pyramidal supercrystals. Rhombic dodecahedral, octahedral, and hexapod-shaped supercrystals were generated through the assembly of octahedra. Corner-truncated octahedra formed tetrapod-shaped supercrystals at room temperature, but octahedral, truncated triangular pyramidal, and square pyramidal supercrystals at 90 °C. Nanocrystal assembly was found to be strongly shape-guided. Expulsion of excess surfactant to the surfaces of supercrystals suggests that responsive adjustment of surfactant concentration during particle assembly mediates supercrystal formation. Transmission X-ray microscopy and optical microscopy have been employed to follow the supercrystal formation process. Surprising rotational water current near the droplet perimeter carrying the initially formed supercrystals has been observed. Supercrystals appear to grow from the edge of the droplet toward the central region. Supercrystals assembled from octahedra inherently contain void spaces and possibly connected channels. The mesoporosity of these supercrystals was confirmed by infiltrating H(2)PdCl(4) into the supercrystal interior and reducing the precursor to form Pd nanoparticles. The embedded Pd particles can still catalyze a Suzuki coupling reaction, demonstrating the application of these supercrystals for molecular transport, sensing, and catalysis.
Lithium dendrite growth dynamics on Cu surface is first visualized through a versatile and facile experimental cell by in operando transmission X-ray microscopy (TXM). Galvanostatic plating and stripping cycle(s) are applied on each cell. Upon plating/stripping at ∼1 mA cm −2 , mossy lithium is clearly found growing and shrinking on the Cu surface as the application time increases. It is interesting to note that the aspect ratio (height/width) of deposited lithium has increased with charge passed during plating, indicating a faster growing from the base. In addition, the dendritic or mossy lithium has also been observed when various high current densities (25, 12.5, and 6.3 mA cm −2 ) are applied in different cycles, showing a severe dendritic lithium formation that could be induced by inhomogeneous current distribution. The clear structure of dead lithium is found after the cycling, which also shows a lower efficiency and higher hazard when a higher current density is applied. This work explores TXM as a useful tool for in operando dynamic visualization and quantitative measurement of lithium dendrite, which is difficult to achieve with ex situ measurements and other microscopy techniques. The understanding of the growth mechanism from TXM can be beneficial for the development of safe lithium ion and lithium metal batteries.
Sn-containing compounds are potential high-capacity anode materials for Li-ion batteries. They, however, suffer from significant dimensional variations during electrochemical lithiation and delithiation, causing cycling instability. Understanding the dynamics of these deformation processes may provide valuable information in the establishment of viable high-energy anodes. In this paper, the evolution of interior microstructures of two types of Sn-containing particles, including Sn and SnSb, during initial cycles of electrochemical lithiation/delithation has been revealed by in situ synchrotron transmission X-ray microscopy, complemented by in situ synchrotron X-ray diffraction to provide phase information. The microstructures and deformation rates are shown to depend on particle composition, size, and alloy stoichiometry with Li. During first lithiation, both particles exhibit core (metal)–shell (lithiated compounds) interior structures. Initial formation of a dense surface layer containing Li x Sn phases of low Li-stoichiometry on the Sn particle hinders further lithiation kinetics, resulting in delayed expansion of large particles. In contrast, Sb in SnSb is readily lithiated to form a porous Li-rich (Li3Sb) surface layer at higher potential than Sn, which enables the acceleration of lithiation and removal of the size dependence of the lithiation process. Both lithiated particles only partially contract upon delithiation, and their interiors evolve into porous structures due to metal recrystallization. Such porous structures allow for fast lithiation and mitigated dimensional variations upon subsequent cycles. Neither of the two anode particles pulverize upon cycling.
Cubic and octahedral Cu2O nanocrystals and Au–Cu2O core–shell heterostructures are used as sacrificial templates for the growth of Cu2S nanocages and Au–Cu2S core–cage structures. A rapid sulfidation process involving a surface reaction of Cu2O nanocrystals with Na2S, followed by etching of the Cu2O cores with HCl solution for ≈5 sec, results in the fabrication of Cu2S cages with a wall thickness of 10–20 nm. Transmission electron microscopy characterization reveals the formation of crystalline walls and the presence of ultrasmall pores with sizes of 1 nm or less. Formation of Cu2O–Cu2S core–shell structures and their conversion into Cu2S cages is verified by UV–vis absorption spectroscopy. X‐ray photoelectron spectra further confirm the composition of the cages as Cu2S. The entire hollowing process via the Kirkendall effect is recorded using in‐situ transmission X‐ray microscopy. After shell formation, continuous ionic diffusion removes the interior Cu2O. Intermediate structures with remaining central Cu2O portions and bridging arms to the surrounding cages are observed. The nanocages are also shown to allow molecular transport: anthracene and pyrene penetration into the cages leads to enhanced fluorescence quenching immediately upon adsorption onto the surfaces of the encapsulated gold nanocrystals.
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