Visible light photocatalytic cross-coupling and addition reactions of arylalkynes with perfluoroalkyl iodides have been developed. Through slight modification of the reaction conditions, reactions that are selective for the preparation of...
A series of luminescent bis(isocyanoborato) rhenate-(I) phenanthroline complexes with the general formula of cis,trans-[Re(CO) 2 (CNBR 3 ) 2 (phen)]K (R = C 6 F 5 and C 6 H 5 ) have been designed and synthesized. The solutions of these complexes exhibit MLCT phosphorescence. Detailed anion titration study showed that the emission intensity of bis(isocyanotriphenylborato) complex in CH 3 CN/H 2 O solution would be significantly decreased in the presence of cyanide anion, while such a change would not be observed in the presence of other anions including F
The successful generation of perfluoroalkyl radical (Rf) through photoredox catalysis has inspired us to investigate the preparation of various organolfuorine species. In this work, visible light-induced photocatalytic reactions for the...
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