A new class of luminescent cyclometalated Ir(iii) complexes with readily tunable mechanochromic properties derived from the mechanically induced trans-to-cis isomerization have been developed.
Visible light photocatalytic cross-coupling and addition reactions of arylalkynes with perfluoroalkyl iodides have been developed. Through slight modification of the reaction conditions, reactions that are selective for the preparation of...
The successful generation of perfluoroalkyl radical (Rf) through photoredox catalysis has inspired us to investigate the preparation of various organolfuorine species. In this work, visible light-induced photocatalytic reactions for the...
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