Measurements of 81Kr/Kr in deep groundwater from the Nubian Aquifer (Egypt) were performed by a new laser‐based atom‐counting method. 81Kr ages range from ∼2 × 105 to ∼1 × 106 yr, correlate with 36Cl/Cl ratios, and are consistent with lateral flow of groundwater from a recharge area near the Uweinat Uplift in SW Egypt. Low δ2H values of the 81Kr‐dated groundwater reveal a recurrent Atlantic moisture source during Pleistocene pluvial periods. These results indicate that the 81Kr method for dating old groundwater is robust and such measurements can now be applied to a wide range of hydrologic problems.
[1] Measurements of radiochlorine ( 36 Cl), radiogenic noble gases ( 4 He and 40 Ar), and stable chlorine isotope ratios were obtained to assess the residence time of groundwater in the Nubian Aquifer of the Western Desert of Egypt. Measured 36 Cl/Cl ratios yield apparent residence times from $0.2 to 1.2 Â 10 6 years in the deep (600-1200 m) groundwater (assuming constant Cl) and 0.16 Â 10 6 years in the shallow (<600 m) groundwater. Values of d 37 Cl in the groundwater strengthen the application of the 36 Cl dating method by constraining Cl sources and identifying groundwater mixing. Dissolved gases were measured in some of the deep groundwater samples. Measured 4 He concentrations indicate accumulation of radiogenic 4 He that is qualitatively consistent with the age progression indicated by the 36 Cl/Cl ratios, but the flux of external 4 He from the underlying crust has not been quantified and is not constant throughout the aquifer. Concentrations of 40 Ar range from 3.3 to 6.7 Â 10 À4 ccSTP/g and indicate excess air incorporation at recharge. Measured 40 Ar/ 36 Ar ratios do not exceed the atmospheric ratio. A two-dimensional numerical hydrodynamic transect of the aquifer was modeled from the area of the Uweinat Uplift to the northern Bahariya Oasis. Predicted groundwater velocities in the deep portion of the aquifer are 0.5-3.5 m/yr with groundwater residence times up to 9 Â 10 5 years; residence times up to 1.3 Â 10 6 years are predicted in the confining shale. Aquifer properties are estimated by using the model to fit the measured 36 Cl/Cl ratios. Under these conditions, hydrodynamic residence times are within about 30% of those calculated from 36 Cl when mixing of Cl À is accounted for in the highest-Cl À deep groundwaters. By mutually calibrating multiple methods (hydrodynamic, 36 Cl, and 4 He), a consistent picture of the Nubian Aquifer has emerged in which lateral flow from a G 3
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.