Wettability is an important factor affecting the performance of catalytic oxidative desulfurization. In order to develop an efficient catalyst for the extractive coupled catalytic oxidative desulfurization (ECODS) of fuel oil by H2O2 and acetonitrile, a novel family of imidazole-based polyoxometalate dicationic ionic liquids (POM-DILs) [Cn(MIM)2]PW12O40 (n = 2,4,6) was synthesized by modifying phosphotungstic acid (H3PW12O40) with double imidazole ionic liquid. These kinds of catalysts have good dispersity in oil phase and H2O2, which is conducive to the deep desulfurization of fuel oil. The catalytic performance of the catalysts was studied under different conditions by removing aromatic sulfur compound dibenzothiophene (DBT) from model oil. Results showed that [C2(MIM)2]PW12O40 had excellent desulfurization efficiency, and more than 98% of DBT was removed under optimum conditions. In addition, it also exhibited good recyclability, and activity with no significant decline after seven reaction cycles. Meanwhile, dibenzothiophene sulfone (DBTO2), the only oxidation product of DBT, was confirmed by Gas Chromatography-Mass Spectrometry (GC-MS), and a possible mechanism of the ECODS process was proposed.

In this study, a novel phosphotungstic acid based dicationic ionic liquid [C2(MIM)2]PW12O40 was successfully prepared and immobilized on graphitic carbon nitride (g-C3N4). The supported catalysts wt% [C2(MIM)2]PW12O40/g-C3N4 (wt=3%, 10%, 30%,...

A novel supported deep eutectic solvent (DES) TBAB/PEG-200 was prepared by loading DES TBAB/PEG-200 onto mesoporous silica by sol-gel method. The properties of the supported deep eutectic solvent TBAB/PEG-200 were...

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Green, efficient and inexpensive desulfurizing solvents have always been a considerable focus of petroleum desulfurization research.

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Hexamethylol melamine resins (HMM) with low crystallization water content and low viscosity were prepared by inhibiting the condensation polymerization of low hexamethylol melamine. The effects of catalyst, pH, formalde-hyde/melamine ratio, reaction temperature and time on the synthesis parameters of HMM were investigated. The results showed that the sample (HMM8) synthesized with Na2CO3-NaHCO3 as catalyst had the crystallization water content lower than 10%, being with a viscosity of about 0.26 Pa·s. The melting temperature of HMM8/polyvinyl alcohol (PVA) curing system was about 164.3 °C. It was found that the higher the amount of formaldehyde, the greater the hydroxyl methyl bounded to each triazine ring. Compared with the traditional melamine formaldehyde resin which had the crystallization water content of about 20–30%, the production of this resin was expected to reduce the energy consumption of industrial reaction, while the resin with 10% crystallization water content was more conducive to the development of alloying HMM/PVA composite membrane.

A series of novel modified amphiphilic quaternary ammonium phosphotungstate catalysts with Keggin structure were synthesized. The physical and chemical properties were characterized by FT-IR, XRD, SEM, and TG-DSC. Heterogeneous catalytic...