Multiwalled carbon nanotubes activated by KOH (CNTs-KOH) were synthesized and employed as adsorbents to study adsorption characteristics of toluene, ethylbenzene, and m-xylene (TEX) from aqueous solutions. Kinetics data were fitted by pseudo-second-order model, and intraparticle diffusion was not the only rate-controlling step. Adsorption isotherm data could fit well with Langmuir, Freundlich, and Dubinin-Radushkevich (D-R) models. The maximum adsorption capacities on CNTs-KOH are 87.12, 322.05, and 247.83 mg/g for toluene, ethylbenzene, and m-xylene, respectively. The adsorption capacities of TEX onto CNTs-KOH increased with contact time and decreased with temperature and are not significantly affected by humic acid. However, Cr(6+) could decrease adsorption of TEX by 17.66, 4.51, and 12.69% as (K(d)(1) - K(d)(2))/K(d)(1), respectively. The thermodynamics parameters indicated that adsorption was a feasible, exothermic, and spontaneous process in nature and a physisorption process. The present CNTs-KOH show a better EX adsorption performance than other adsorbents, suggesting that CNTs-KOH are promising EX adsorbents in wastewater treatment.
This paper summarizes the main features of water resources management of the Pearl River basin in southern China. A regulation over the basin through integrating various regions was first established for enhancing the water resources management. Based on such a regulation, a public policy frame was then constructed aiming for the harmony between human activities and nature. It is hoped that, as a result, the basin's socio-economic sustainable development could be achieved. In practice, the Pearl River Water Resources Commission (PRWRC), which is the basin regulatory authority, has been focusing on various aspects of regulating water basin and conserving water resources. These aspects include the development of innovative regulations of treating water, exploration of compensation schemes for water resources prevention, investigation of the hydraulic engineering project impacts on region relocation and ecology, and establishment of marketing schemes for sustainable application of water resources. It is expected that these regulating water resources aspects would result in enhancing public participation and negotiation in the Pearl River basin management. A case study is presented on the PRWRC's effort in coordinating water discharges from a number of reservoirs to protect the safe water supply in the Pearl River basin from seawater intrusion during the dry season.
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