Monolayer transition metal dichalcogenides (TMDCs) with high crystalline quality are important channel materials for next‐generation electronics. Researches on TMDCs have been accelerated by the development of chemical vapor deposition (CVD). However, antiparallel domains and twin grain boundaries (GBs) usually form in CVD synthesis due to the special threefold symmetry of TMDCs lattices. The existence of GBs severely reduces the electrical and photoelectrical properties of TMDCs, thus restricting their practical applications. Herein, the epitaxial growth of single crystal MoS2 (SC‐MoS2) monolayer is reported on Au (111) film across a two‐inch c‐plane sapphire wafer by CVD. The MoS2 domains obtained on Au (111) film exhibit unidirectional alignment with zigzag edges parallel to the <110> direction of Au (111). Experimental results indicated that the unidirectional growth of MoS2 domains on Au (111) is a temperature‐guided epitaxial growth mode. The high growth temperature provides enough energy for the rotation of the MoS2 seeds to find the most favorable orientation on Au (111) to achieve a unidirectional ratio of over 99%. Moreover, the unidirectional MoS2 domains seamlessly stitched into single crystal monolayer without GBs formation. The progress achieved in this work will promote the practical applications of TMDCs in microelectronics.
We analyzed the protective ability of chemical vapor deposition (CVD) graphene domains against corrosion of Cu surfaces. Fresh graphene domains of various shapes were ideal corrosion-inhibiting layers. However, obvious corrosion was found within graphene domains exposed to the air for over a week. Our work demonstrates that the opportunities for corrosion of CVD graphene were provided by wrinkles but not others, such as Cu grain boundaries and graphene domain boundaries, which are always believed the primary factor for inferior quality of the CVD graphene at present.
In situ oceanographic measurements were made before and after the passage of Typhoon Wutip in September 2013 over the northern South China Sea. The surface geostrophic circulation over this region inferred from satellite altimetry data features a large‐size anticyclonic eddy, a small‐size cyclonic eddy, and smaller‐size eddies during this period. Significant typhoon‐induced changes occurred in the partial pressure of CO2 at the sea surface (pCO2sea) during Wutip. Before the passage of Wutip, pCO2sea was about 392.92 ± 1.83, 390.31 ± 0.50, and 393.04 ± 4.31 μatm over the cyclonic eddy water, the anticyclonic eddy water, and areas outside two eddies, respectively. The entire study region showed a carbon source (1.31 ± 0.46 mmol CO2 m−2 d−1) before Wutip. In the cyclonic eddy water after Wutip, high sea surface salinity (SSS), low sea surface temperature (SST), and high pCO2sea (413.05 ± 7.56 μatm) made this area to be a carbon source (3.30 ± 0.75 mmol CO2 m−2 d−1). In the anticyclonic eddy water after Wutip, both the SSS and SST were lower, pCO2sea was also lower (383.03 ± 3.72 μatm), and this area became a carbon sink (–0.11 ± 0.55 mmol CO2 m−2 d−1), in comparison with the pretyphoon conditions. The typhoon‐induced air‐sea CO2 flux reached about 0.03 mmol CO2 m−2 d−1. Noticeable spatial variations in pCO2sea were affected mainly by the typhoon‐induced mixing/upwelling and vertical stratifications. This study suggests that the local air‐sea CO2 flux in the study region was affected significantly by oceanographic conditions during the typhoon.
The study of flexible and stretchable strain sensors is growing rapidly owing to the demands for human motion detection, human–machine interaction, and soft robotics. However, super‐stretchable and highly sensitive strain sensors with high linearity and low hysteresis are especially lacking, which therefore limits the use of soft strain sensors in varied practical applications. The stretchability and sensitivity of the capacitive strain sensor are constrained by the material characteristics and structure of parallel plate capacitor (theoretical gauge factor [GF] is 1). To address these limitations, a super‐stretchable and highly sensitive capacitive strain sensor composed of two strips of wrinkled carbon nanotubes‐based electrodes separated by a tape dielectric, is presented. By integrating nanomaterials and wrinkled film structure, this device achieves a GF of 2.07 at 300% strain with excellent linearity and negligible hysteresis. This is the first type of capacitive strain sensors that can achieve super‐stretchability and sensitivity simultaneously. Additionally, the sensor has a fast signal response time of ≈80 ms, and good mechanical durability during 1000 stretching and releasing cycles. The authors demonstrate the use of this sensor as a versatile wearable device for human motion tracking, and as a smart real‐time monitoring device for soft pneumatic robots.
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