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Hexabromocyclododecane (HBCDD), as one of the most widely used brominated flame retardants (BFRs), is of great concern globally because of its persistence in the environment and negative impacts on humans and animals. HBCDD has been mainly used in flame-retarded expanded (EPS) and extruded (XPS) polystyrene foams for insulation in the construction industry. Most of these products will become a part of the construction and demolition (C&D) waste at the end of their life cycle (30-50 years) which is typically disposed of into landfills or incineration. However, the recycling of this material takes quite a low share compared with landfill and incineration. Consequently, high environmental risks will exist in these disposal approaches due to the HBCDD in C&D waste. Currently, XPS or EPS products containing HBCDD in the construction industry have not reached the end of their life cycle in most countries. Relatively little attention has been paid to this emergency issue by either the government or public. Furthermore, C&D waste is most likely disposed of by direct dumping, simple stacking, or open burning in developing countries. Therefore, this paper highlights the global environmental risks of HBCDD from C&D waste. Areas of research for key problems of HBCDD contained in C&D waste are suggested to help control and finally eliminate the impact.