The increasing threat of antibiotic-resistant bacterial strains represents the current antibacterial dilemma and requires novel bactericidal treatment to circumvent this problem. In this work, an efficient strategy to kill bacteria...
Controllable actuation and coordinating motion of artificial self-propelled micro/nanomotors to mimic the motile natural microorganism systems are of great significance for constructing intelligent nanoscale machines. In particular, inorganic oxide particles have shown considerable promise in implementation of synthetic micro/nanomotors, due to their unique features and active response to environmental stimuli. This work critically reviews the recent progress in inorganic oxide-based micro/nanomotors and focuses on their propulsion response to chemical and physical stimuli, especially emphasizing and discussing operating principles in the single engine, adaptive navigation under composite-driven powers, and intriguing collective behaviors. The impact of oxide structure, multiple fields in motion controllability, and interaction between grouped micro/nanomotors are explored. Practical applications of individual and assembled micro/nanomotors in environmental and biomedical fields are demonstrated, including the removal of pollutants, drug delivery, cancer therapy, and in vivo imaging. Finally, current challenges for the development of novel micro/nanomotors and possible constraints toward the defined structure and accumulated toxicity are discussed along with future opportunities and directions. Owing to their facile synthesis, impressive physicochemical performances, high biocompatibility, and versatile actuations, it is expected that the association of inorganic oxides with micro/nanomotors will bring new and unique capabilities to the field of active matter.
This paper primarily investigates the effects of chemically grafted modified carbon fibers on the bonding properties of fiber metal laminates (FMLs). Relative elemental content on the carbon fibers’ surface was performed via X-ray photoelectron spectroscopy (XPS). Scanning electron microscopy (SEM) was utilized to observe the material microstructure. The effect of chemically grafted carbon fibers on the bond strengths of FMLs was experimentally investigated through lap joint testing. The carbon nanotubes (CNTs) grafting concentration and curing conditions of the samples were also investigated. The test results demonstrate that grafting concentrations of 0.1, 0.2, and 0.3 mg/mL CNT solution increased the bond strength of the cured samples under vacuum conditions by 63.51%, 87.16%, and 71.56%, respectively. In addition, the bond strengths of vacuum-cured samples were also increased.
A magnetic metal−organic frameworks adsorbent (Fe3O4@MIL-53(Al)) was prepared by a typical solvothermal method for the removal of bisphenol A (BPA), tetracycline (TC), congo red (CR), and methylene blue (MB). The prepared Fe3O4@MIL-53(Al) composite adsorbent was well characterized by scanning electron microscope (SEM), transmission electron microscope (TEM), X-ray diffraction (XRD), and fourier transform infrared spectrometer (FTIR). The influence of adsorbent quantity, adsorption time, pH and ionic strength on the adsorption of the mentioned pollutants were also studied by a UV/Vis spectrophotometer. The adsorption capacities were found to be 160.9 mg/g for BPA, 47.8 mg/g for TC, 234.4 mg/g for CR, 70.8 mg/g for MB, respectively, which is superior to the other reported adsorbents. The adsorption of BPA, TC, and CR were well-fitted by the Langmuir adsorption isotherm model, while MB followed the Freundlich model, while the adsorption kinetics data of all pollutants followed the pseudo-second-order kinetic models. The thermodynamic values, including the enthalpy change (ΔH°), the Gibbs free energy change (ΔG°), and entropy change (ΔS°), showed that the adsorption processes were spontaneous and exothermic entropy-reduction process for BPA, but spontaneous and endothermic entropy-increasing processes for the others. The Fe3O4@MIL-53(Al) was also found to be easily separated after external magnetic field, can be a potential candidate for future water treatment.
Iron is one of the trace elements required by human body, and its deficiency can lead to abnormal bone metabolism. In this study, the effect of iron ions on the properties of tricalcium silicate bone cement (Fe/C3Ss) was investigated. It effectively solved the problems of high pH value and low biological activity of calcium silicate bone cement. The mechanical properties, in vitro mineralization ability and biocompatibility of the materials were systematically characterized. The results indicate that tricalcium silicate bone cement containing 5 mol% iron displayed good self-setting ability, mechanical properties and biodegradation performance in vitro. Compared with pure calcium silicate bone cement (C3Ss), Fe/C3Ss showed lower pH value (8.80) and higher porosity (45%), which was suitable for subsequent cell growth. Immersion test in vitro also confirmed its good ability to induce hydroxyapatite formation. Furthermore, cell culture experiments performed with Fe/C3Ss ion extracts clearly stated that the material had excellent cell proliferation abilities compared to C3Ss and low toxicity. The findings reveal that iron-doped tricalcium silicate bone cement is a promising bioactive material in bone repair applications.
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