Oxovanadium(V) complexes and with general formula VO(L3*)(OR5) were prepared in quantitative yields in alcohol (R5OH) from reactions of VO(O-i-Pr)3 and tridentate Schiff bases of beta-amino alcohols having one or two stereogenic centers, (HO)C*(R1)(R2)C*H(R3)N[double bond, length as m-dash]CH(2-OH-3,5-R4(2)-C6H2) (H2L3*). The alkoxy OR5 ligand exchanges readily with the alcoholic molecule in the solvent. Crystal structures of and were determined to be five-coordinate square pyramidal monomers. However, 1H NMR spectra of the complexes reveal two sets of signals, indicating the presence of two isomers in solution. The two isomers are suggested to be the endo/exo pair or the monomer/dimer pair. Asymmetric oxidations of methyl phenyl sulfide catalyzed by catalyst precursors were demonstrated to afford the chiral sulfoxide in yields and ee values similar to those obtained from the in situ-formed catalytic systems of VO(acac)2 and corresponding Schiff base ligands. Complexes and are also good catalysts for asymmetric alkynyl additions to aldehydes. Structural differences between the oxovanadium complexes, for inducing high stereoselectivities in the asymmetric oxidation of organic sulfides and the asymmetric alkynyl addition to aldehydes, are rationalized.
Voltage reduction (2.4 V at 2 mA/cm 2 ) and efficiency improvement (7-times) were demonstrated in blue QLEDs by positive aging process, which came from (1) improvement of carrier injection at ZnO/QD interface and/or carrier transport in QD layer, and (2) enhancement of PLQY of QD emissive layer.
KeywordsQLED; blue emission; high efficiency; positive aging. P-108 / W.-C. Ding SID 2018 DIGEST • 1623
By combining stable array processes and cutting-edge OLED processes, we successfully fabricated a high-performance 65-inch ultra HD TV with excellent visual quality. Our discussion will briefly explain the architecture of the OLED TV and its merits.
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