Conversion electron Mössbauer spectroscopy (CEMS) and x-ray diffraction were used to study a series of rf-reactively sputtered FeAlN thin films with the goal of gaining insight into the origins of their uniaxial magnetic anisotropy (UMA) and the effect of sputtering conditions on its thermal stability. At N/Fe=4.6%(±0.5%), N goes into interstitial vacancies without significant reductions in the hyperfine field (Bhf) of the Fe but causing lattice expansions, leading to an increased linewidth in the CEMS spectra of the film while the sample has an in-plane UMA. Reducing the target-to-substrate spacing used in the deposition process does not affect the nitrogen content of the films but yields an increased CEMS linewidth reflecting larger disorder in the local Fe environment. Heavy N doping causes the phase transform into γ′-Fe4N, ε-Fe3N, and ζ-Fe2N phases. A well defined UMA exists in mildly doped FeAlN films when doped N atoms mostly occupy the interstitial sites while FeAl and heavily doped FeAlN films are either isotropic or weakly anisotropic. UMA and its thermal stability are therefore concluded to have a correlation with the local environment of the Fe structure induced by N doping.
We report the epitaxial growth of high quality Fe thin films on both n-type GaAs(001) and GaAs(011) substrates using electrochemical deposition. X-ray diffraction shows Fe(001)[110]//GaAs(001)[110] and Fe(011)[100]//GaAs(011)[100] as the primary epitaxial relations similarly to Fe films grown by molecular-beam epitaxy. The structural quality depends on the composition of the plating solution. The Hc values of these films are around 30–100 Oe. The 4πMs value is about 20–21 kG. In-plane angular ferromagnetic resonance measurements showed crystalline anisotropy for both the Fe(001) and Fe(011) films which is superimposed by a substrate induced uniaxial anisotropy for the Fe(011) layers.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.
hi@scite.ai
10624 S. Eastern Ave., Ste. A-614
Henderson, NV 89052, USA
Copyright © 2024 scite LLC. All rights reserved.
Made with 💙 for researchers
Part of the Research Solutions Family.