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The mechanism of ambient pressure encapsulation of He and Ne in the R and β crystalline cages of type-A zeolites is demonstrated. Reversible and highly selective gas admission and entrapment are readily achieved at characteristic temperatures occurring between 77 and 570 K. The permeability of the zeolitic windows is governed by an interplay between the critical diameter of the encapsulate and the effective apertures dimension, which is shown to be strongly dependent on temperature. The blocking state of the zeolitic apertures is determined by a simultaneous thermal activation of both cation mobility and structural dilation/constriction of crystalline windows. Encapsulation in NaA (4A) principally occurs in the β cages of the Sodalite units, whereas the K-exchange form (3A) offers both R and β encapsulations. The effective free aperture dimension of the Ca exchange form (5A) is found to be too large to allow a practical gas enfoldment in either class of cavities, even at 77 K, where only poor encapsulation is observed. The counterion location vs size dependence, known only from crystallographic data, is sensed here for the first time by an encapsulation process, via the manifestation of different aperture occupancy states. While the blocking extent of the wider O 8 windows of the R cages is consistent with the size of exchangeable cations, a reverse correlation is evident for the narrower O 6 windows of the β cages.

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Myotonic dystrophy, a rare genetic disorder, may pose a serious problem to the anaesthesiologist due to muscular and extramuscular involvement. Thirteen patients, median age 21 yr were anaesthetized by continuous propofol infusion, fentanyl, atracurium and N2O to evaluate this combination in myotonic dystrophy. Intraoperatively, neither exaggerated reactions nor haemodynamic instability was observed. Recovery was smooth and quick. Although there was a significant decrease in mean postoperative vital capacity (965 (349) ml) from the preoperative value (1664 (566) ml, P = 0.0028), there was no change in mean postoperative SpO2 and there were no perioperative respiratory complications. Only two patients complained of nausea and vomiting. Similarly, muscular hypertonia and shivering were not observed. We conclude that the combination of continuous propofol infusion and fentanyl was a successful anaesthetic technique in these young myotonic dystrophy patients undergoing peripheral surgery.

High-gradient insulators HGI are periodic assemblies of conducting and insulating layers that have been shown to withstand higher pulsed voltages in vacuum than homogeneous insulators of the same length. We carried out calculations and experimental studies to understand the effect of geometry on the performance of wellconditioned, flat-surface HGI assemblies. We tested stacks with several different ( values of Ir r r r rM where I is the axial length of an insulating layer and M is the length ) of a metal layer . The experiments showed that HGI performance was substantially better than conventional insulators for Ir r r r rM -3 and somewhat worse for Ir r r r rM ) ) 3. Numerical calculations of electron orbits showed: 1 that the electric fields in HGI assemblies may have the favorable property of sweeping charged particles away ) from the surface and 2 that electron multiplication on the surface is suppressed when Ir r r r rM -3.Index Terms -High voltage insulators, electron avalanche, vacuum surface breakdown.

We calculated the proton kinetic energies Ke(H) of ice under high pressures up to 63 GPa by assuming the harmonic approximation. The input measured optical frequencies of vibration, libration, and translation of ice VII versus pressure as well as the H2O geometry and the distances R(OH) necessary for calculating Ke(H) (at 298 K) were taken from the literature. The resulting Ke(H) values were found to decrease gradually with increasing pressure, approaching the region where the H-atom is symmetrically hydrogen bonded between two oxygens in the OH-O system. Interestingly, the Ke(H) results were found to be consistent with those of other materials such as Rb3H(PO4)2 and KH2PO4 having similar R(OH) and R(OO) distances in the OH-O system. Similar calculations were also carried out for D2O.

Monensin is an ionophore that supports an electroneutral ion exchange across the lipid bilayer. Because of this, under steady-state conditions, no electric signals accompany its reactions. Using the Laser Induced Proton Pulse as a synchronizing event we selectively acidify one face of a black lipid membrane impregnated by monensin. The short perturbation temporarily upsets the acid-base equilibrium on one face of the membrane, causing a transient cycle of ion exchange. Under such conditions the molecular events could be discerned as a transient electric polarization of the membrane lasting approx. 200 microseconds. The proton-driven chemical reactions that lead to the electric signals had been reconstructed by numeric integration of differential rate equations which constitute a maximalistic description of the multi equilibria nature of the system (Gutman, M. and Nachliel, E. (1989) Electrochim. Acta 34, 1801-1806). The analysis of the reactions reveals that the ionic selectivity of the monensin (H+ > Na+ > K+) is due to more than one term. Besides the well established different affinity for the various cations, the selectivity is also derived from a large difference in the rates of cross membranal diffusivities (MoH > MoNa > MoK), which have never been detected before. (v) Quantitative analysis of the membrane's crossing rates of the three neutral complexes reveals a major role of the membranal dipolar field in regulating ion transport. The diffusion of MoH, which has no dipole moment, is hindered only by the viscose drag. On the other hand, the dipolar complexes (MoNa and MoK) are delayed by dipole-dipole interaction with the membrane. (vi) Comparison of the calculated dipoles with those estimated for the crystalline conformation of the [MoNa(H2O)2] and [MoK(H2O)2] complexes reveals that the MoNa may exist in the membrane at its crystal configuration, while the MoK definitely attains a structure having a dipole moment larger than in the crystal.

The He͑Ne͒/NaA-zeolite system was studied using temperature programmed desorption mass spectrometry ͑TPD-MS͒ with a supersonic molecular-beam inlet. Controllable, stable, and reversible entrapment of He and Ne by the ␤ cages of NaA zeolite was experimentally achieved at ambient pressure and around 200°C. Decapsulation of either He or Ne from NaA is shown to be of a doublet character, indicating on the occurrence of effectively two classes of ␤ cavities: completely blocked cages, never previously observed, and partly blocked ones. The encapsulation of Ne and He in NaA is associated with the coupling of two reversible mechanisms governing the effective free aperture dimension, i.e., apertures thermal dilation and activated ion mobility. Characteristic admission temperatures between 130°C and 200°C, show highly selective sieving effect between He and Ne, suggesting its potential utilization for gas separation via a temperature swing practice and for a possible experimental realization of quantum sieving.