A new microchannel with a series of symmetric sharp corner structures is reported for passive size-dependent particle separation. Micro particles of different sizes can be completely separated based on the combination of the inertial lift force and the centrifugal force induced by the sharp corner structures in the microchannel. At appropriate flow rate and Reynolds number, the centrifugal force effect on large particles, induced by the sharp corner structures, is stronger than that on small particles; hence after passing a series of symmetric sharp corner structures, large particles are focused to the center of the microchannel, while small particles are focused at two particle streams near the two side walls of the microchannel. Particles of different sizes can then be completely separated. Particle separation with this device was demonstrated using 7.32 μm and 15.5 μm micro particles. Experiments show that in comparison with the prior multi-orifice flow fractionation microchannel and multistage-multiorifice flow fractionation microchannel, this device can completely separate two-size particles with narrower particle stream band and larger separation distance between particle streams. In addition, it requires no sheath flow and complex multi-stage separation structures, avoiding the dilution of analyte sample and complex operations. The device has potentials to be used for continuous, complete particle separation in a variety of lab-on-a-chip and biomedical applications.
The conventional methods of creating superhydrophobic surface-enhanced Raman spectroscopy (SERS) devices are by conformally coating a nanolayer of hydrophobic materials on micro-/nanostructured plasmonic substrates. However, the hydrophobic coating may partially block hot spots and therefore compromise Raman signals of analytes. In this paper, we report a partial Leidenfrost evaporation-assisted approach for ultrasensitive SERS detection of low-concentration analytes in water droplets on hierarchical plasmonic micro-/ nanostructures, which are fabricated by integrating nanolaminated metal nanoantennas on carbon nanotube (CNT)decorated Si micropillar arrays. In comparison with natural evaporation, partial Leidenfrost-assisted evaporation on the hierarchical surfaces can provide a levitating force to maintain the water-based analyte droplet in the Cassie−Wenzel hybrid state, i.e., a Janus droplet. By overcoming the diffusion limit in SERS measurements, the continuous shrinking circumferential rim of the droplet, which is in the Cassie state, toward the pinned central region of the droplet, which is in the Wenzel state, results in a fast concentration of dilute analyte molecules on a significantly reduced footprint within several minutes. Here, we demonstrate that a partial Leidenfrost droplet on the hierarchical plasmonic surfaces can reduce the final deposition footprint of analytes by 3−4 orders of magnitude and enable SERS detection of nanomolar analytes (10 −9 M) in an aqueous solution. In particular, this type of hierarchical plasmonic surface has densely packed plasmonic hot spots with SERS enhancement factors (EFs) exceeding 10 7 . Partial Leidenfrost evaporation-assisted SERS sensing on hierarchical plasmonic micro-/nanostructures provides a fast and ultrasensitive biochemical detection strategy without the need for additional surface modifications and chemical treatments.
In this work, we use molecular dynamics simulations to investigate coalescence-induced jumping of nanodroplets on curved surfaces with different wettabilities. On a curved surface, a liquid bridge will first form between two coalescing droplets as on a flat surface. However, contrary to symmetry-breaking-induced jumping on a flat surface, coalescing droplets would jump earlier than the liquid bridge gets into contact with the curved surface. Such an early symmetry breaking is induced by the opposite motion of coalescing droplets along the lateral direction on the curved surface. We find that surface curvature can effectively facilitate the jumping of coalescing nanodroplets via enhanced symmetry breaking. The energy conversion efficiency is improved from ∼0.15% on a flat surface to ∼2.9% on a curved surface, which is about 20 times enhancement. In addition, we conducted an energy scaling analysis by considering the lumped effects of both viscous dissipation and contact line friction on the jumping behaviors. We conclude that curvature-enhanced jumping in the nanoscale can be ascribed to the mitigated contact line dissipation E cl, whereas viscous dissipation E vis is maintained almost at the same level. Therefore, we unveil a scaling law between the energy conversion efficiency η on surfaces with different curvatures and the product of contact line length and contact time. Interestingly, the increasing surface curvature could allow the occurrence of coalescence-induced jumping on a less superhydrophobic surface. Hence, a phase map of coalescence-induced jumping in terms of surface curvature ratio and surface wettability is presented. Essentially, the paradigm of curved surfaces in the nanoscale used in this study is characteristic of the topography of micro/nanostructured surfaces, on which coalescence-induced droplet jumping has been experimentally observed. This work justifies the critical role of nanoroughness in boosting coalescence-induced jumping of nanodroplets and sheds light on the passive control of nanodroplets jumping on functional surfaces.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.
hi@scite.ai
10624 S. Eastern Ave., Ste. A-614
Henderson, NV 89052, USA
Copyright © 2024 scite LLC. All rights reserved.
Made with 💙 for researchers
Part of the Research Solutions Family.