The synthesis, self-assembly, and gelation ability of a series of organogelators based on perylene bisimide (PBI) dyes containing amide groups at imide positions are reported. The synergetic effect of intermolecular hydrogen bonding among the amide functionalities and pi-pi stacking between the PBI units directs the formation of the self-assembled structure in solution, which beyond a certain concentration results in gelation. Effects of different peripheral alkyl substituents on the self-assembly were studied by solvent- and temperature-dependent UV-visible and circular dichroism (CD) spectroscopy. PBI derivatives containing linear alkyl side chains in the periphery formed H-type pi stacks and red gels, whereas by introducing branched alkyl chains the formation of J-type pi stacks and green gels could be achieved. Sterically demanding substituents, in particular, the 2-ethylhexyl group completely suppressed the pi stacking. Coaggregation studies with H- and J-aggregating chromophores revealed the formation of solely H-type pi stacks containing both precursor molecules at a lower mole fraction of J-aggregating chromophore. Beyond a critical composition of the two chromophores, mixed H-aggregate and J-aggregate were formed simultaneously, which points to a self-sorting process. The versatility of the gelators is strongly dependent on the length and nature of the peripheral alkyl substituents. CD spectroscopic studies revealed a preferential helicity of the aggregates of PBI building blocks bearing chiral side chains. Even for achiral PBI derivatives, the utilization of chiral solvents such as (R)- or (S)-limonene was effective in preferential population of one-handed helical fibers. AFM studies revealed the formation of helical fibers from all the present PBI gelators, irrespective of the presence of chiral or achiral side chains. Furthermore, vortex flow was found to be effective in macroscopic orientation of the aggregates as evidenced from the origin of CD signals from aggregates of achiral PBI molecules.

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The dynamics and mobility of excitons in J-aggregates of perylene bisimides are investigated by transient absorption spectroscopy with a time resolution of 50 fs. The transient spectra are compatible with an exciton delocalization length of two monomers and indicate that vibrational and configurational relaxation processes are not relevant for the spectroscopic properties of the aggregates. Increasing the pump pulse energy and in that way the initial exciton density results in an accelerated signal decay and pronounced exciton-exciton annihilation dynamics. Modeling the data by assuming a diffusive exciton motion reveals that the excitons cannot migrate freely in all three directions of space but their mobility is restricted to one dimension. The observed anisotropy supports this picture and points against direct Förster-transfer-mediated annihilation between the excitons. A diffusion constant of 1.29 nm(2)/ps is deduced from the fitting procedure that corresponds to a maximal exciton diffusion length of 96 nm for the measured exciton lifetime of 3.6 ns. The findings indicate that J-aggregates of perylene bisimides are promising building blocks to facilitate directed energy transport in optoelectronic organic devices or artificial light-harvesting systems.

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S U M M A R YRecently, the S receiver function method has been successfully developed to identify upper mantle interfaces. S receiver functions have the advantage of being free of S-wave multiple reflections and can be more suitable than P receiver functions for studying mantle lithosphere. However, because of specific ray geometry and interference of diverse phases, the S receiver function method has some technical difficulties and limitations. We use synthetic seismograms to demonstrate the feasibility and limitations of S receiver functions for studying mantle structures. Full-wavefield seismograms were calculated using the reflectivity method and processed to generate synthetic S receiver functions for S, SKS and ScS waves. Results show that S receiver functions can be obtained from waveforms of S, SKS and ScS waves. The synthetic S receiver functions for these incident waves show S-to-P converted phases at all discontinuities in the crust and upper mantle. Useful ranges of epicentral distances for calculation of S receiver functions are: 55 • -85 • for S, >85 • for SKS and 50 • -75 • for ScS waves. We apply both the S and P receiver function methods to data recorded at broadband station YKW3 in Northwest Canada. The study shows that there is significant agreement among different receiver function methods, and demonstrates the usefulness of S receiver functions for imaging the mantle lithosphere.

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GPS displacement vectors show that the crust in east Tibet is being squeezed in an easterly direction by the northward motion of the Indian plate, and the Sichuan Basin is resisting this stream and redirecting it mainly towards Indochina. The Longmen Shan, containing the steepest rise to the high plateau anywhere in Tibet, results from the strong interaction between the east Tibetan escape flow and the rigid Yangtze block (Sichuan Basin), but the kinematics and dynamics of this interaction are still the subject of some debates. We herein present results from a dense passive-source seismic profile from the Sichuan Basin into eastern Tibet in order to study the deep structure of this collision zone. Using P and S receiver function

The volcanic edifice of the Hawaiian islands and seamounts, as well as the surrounding area of shallow sea floor known as the Hawaiian swell, are believed to result from the passage of the oceanic lithosphere over a mantle hotspot. Although geochemical and gravity observations indicate the existence of a mantle thermal plume beneath Hawaii, no direct seismic evidence for such a plume in the upper mantle has yet been found. Here we present an analysis of compressional-to-shear (P-to-S) converted seismic phases, recorded on seismograph stations on the Hawaiian islands, that indicate a zone of very low shear-wave velocity (< 4 km s(-1)) starting at 130-140 km depth beneath the central part of the island of Hawaii and extending deeper into the upper mantle. We also find that the upper-mantle transition zone (410-660 km depth) appears to be thinned by up to 40-50 km to the south-southwest of the island of Hawaii. We interpret these observations as localized effects of the Hawaiian plume conduit in the asthenosphere and mantle transition zone with excess temperature of approximately 300 degrees C. Large variations in the transition-zone thickness suggest a lower-mantle origin of the Hawaiian plume similar to the Iceland plume, but our results indicate a 100 degrees C higher temperature for the Hawaiian plume.