Graphites with a low degree of graphitization are more appropriate to prepare thin layer graphene with a high degree of defects and high specific capacitance.
Inspired by the structure features of micelle, we attempt to synthesize a novel functionalized mesoporous silica nanosphere consisting of a hydrophobic core and a hydrophilic shell. The obtained solid materials were structurally confirmed by N(2) sorption, X-ray diffraction (XRD), and transmission electron microscopy (TEM). Their compositions were characterized by Fourier transfer infrared spectroscopy (FT-IR), solid state NMR, X-ray photoelectron spectroscopy (XPS), and elemental analysis. Its fundamental properties such as dispersibility in water or organic phase, wettability, and adsorption ability toward hydrophobic organics in water were investigated. It was revealed that these important properties could be facilely adjusted through varying structure and composition. In particular, these materials showed much better adsorption ability toward hydrophobic organic molecules in water than conventional monofunctionalized mesoporous materials, owing to possessing the hydrophobic/hydrophilic domain-segregated and hierarchically functionalized mesoporous structures. The intriguing properties would make mesoporous materials more accessible to many important applications, especially in aqueous systems.
Supercapacitors (SCs) have generated a great deal of interest regarding their prospects for application in energy storage due to their advantages such as long life cycles and high-power density. Graphene is an excellent electrode material for SCs due to its high electric conductivity and highly specific surface area. Conductive polymers (CPs) could potentially become the next-generation SC electrodes because of their low cost, facile synthesis methods, and high pseudocapacitance. Graphene/CP composites show conspicuous electrochemical performance when used as electrode materials for SCs. In this article, we present and summarize the synthesis and electrochemical performance of graphene/CP composites for SCs. Additionally, the method for synthesizing electrode materials for better electrochemical performance is discussed.
A novel solid catalyst featuring a hydrophobic core-hydrophilic shell structure was synthesized for aqueous-phase reactions, which showed significant reaction rate enhancement effects.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.