Single-mode laser is realized in a cesium lead halide perovskite submicron sphere at room temperature. All-inorganic cesium lead halide (CsPbX, X = Cl, Br, I) microspheres with tunable sizes (0.2-10 μm) are first fabricated by a dual-source chemical vapor deposition method. Due to smooth surface and regular geometry structure of microspheres, whispering gallery resonant modes make a single-mode laser realized in a submicron sphere. Surprisingly, a single-mode laser with a very narrow line width (∼0.09 nm) was achieved successfully in the CsPbX spherical cavity at low threshold (∼0.42 μJ cm) with a high cavity quality factor (∼6100), which are the best specifications of lasing modes in all natural nano/microcavities ever reported. By modulating the halide composition and sizes of the microspheres, the wavelength of a single-mode laser can be continuously tuned from red to violet (425-715 nm). This work illustrates that the well-controlled synthesis of metal cesium lead halide perovskite nano/microspheres may offer an alternative route to produce a widely tunable and greatly miniaturized single-mode laser.

Near infrared broadband emission characteristics of bismuth-doped aluminophosphate glass have been investigated. Broad infrared emissions peaking at 1210nm, 1173nm and 1300nm were observed when the glass was pumped by 405nm laser diode (LD), 514nm Ar+ laser and 808nm LD, respectively. The full widths at half maximum (FWHMs) are 235nm, 207nm and 300nm for the emissions at 1210nm, 1173nm and 1300nm, respectively. Based on the energy matching conditions, it is suggested that the infrared emission may be ascribed to 3P1? 3P0 transition of Bi+. The broadband infrared luminescent characteristics of the glasses indicate that they are promising for broadband optical fiber amplifiers and tunable lasers.

Broadband infrared luminescence from bismuth-doped germanium oxide glasses prepared by a conventional melting-quenching technique was discovered. The absorption spectrum of the glasses covered a wide range from the visible to the near-infrared wavelength regions and consisted of five broad peaks below 370, 500, 700, 800, and 1000 nm. The fluorescence spectrum exhibited broadband characteristics (FWHM) greater than 300 nm with a maximum at 1300 nm pumped by an 808-nm laser. The fluorescence lifetime at room temperature decreased with increasing Bi2O3 concentration in the glass. Codoping of aluminum and bismuth was indispensable for the broadband infrared luminescence in GeO2:Bi, Al glass.

We report near infrared broadband emission of bismuth-doped barium-aluminum-borate glasses. The broadband emission covers 1.3microm window in optical telecommunication systems. And it possesses wide full width at half maximum (FWHM) of ~200nm and long lifetime as long as 350micros. The luminescent properties are quite sensitive to glass compositions and excitation wavelengths. Based on energy matching conditions, we suggest that the infrared emission may be ascribed to 3P1? 3P0 transition of Bi+. The broad infrared emission characteristics of this material indicate that it might be a promising candidate for broadband optical fiber amplifiers and tunable lasers.

We report the precipitation and control of metal nanoparticles inside transparent glasses. An Ag ϩ -doped silicate glass sample was first irradiated by using an 800 nm femtosecond laser at room temperature and then annealed at 550°C. The area near the focal point of the laser beam became gray after laser irradiation and yellow after further annealing at 550°C for 10 min. Absorption and electron spin resonance spectra of the glass sample showed that a portion of silver ions near the focused part of the laser beam inside the glass were reduced to silver atoms after the laser irradiation. These silver atoms aggregated to form nanoparticles after further annealing at temperatures above 500°C. A mechanism is suggested that consists of multiphoton reduction, which is induced by the fundamental light of the laser beam and supercontinuum white light, and diffusion of silver atoms driven by heat energy to form nanoparticles. The observed phenomenon may have promising applications for the fabrication of three-dimensional multicolored images inside a transparent material and for integrative micro-optical switches.

No abstract

Nanoparticles have a wide range of electrical and optical properties owing to the quantum-size effect, surface effect, and conjoint effect of nanostructures. [1] Materials doped with noble-metal nanoparticles exhibit large third-order nonlinear

No abstract