A novel char-forming agent named PEIC was designed and synthesized combining pentaerythritol octahydrogen tetraphosphate (PEPA) and tris(2-hydroxyethyl) isocyanurate. PEIC was combined with the silica-gel-microencapsulated ammonium polyphosphate (OS-MCAPP), preparing intumescent flame-retardant polypropylene (PP) composites. The results of the limiting oxygen index (LOI) show that the composite containing 30 wt % IFR with OS-MCAPP:PEIC = 2:1 presents the optimal LOI of 32.7%. Meanwhile, the cone calorimeter tests show that its peak heat release rate is 432 kW m −2 , which decreases by 62.1% compared with that of pure PP, showing a high-efficient flame retardancy. The exhibited UL-94 V-0 rating for all the composites indicates that the IFR composed of PEIC and OS-MCAPP has high-efficient flame retardancy in PP. The analysis of residue char reveals that PEIC could improve the quality of char in compactness, intumescentia, and the degree of graphitization. Further, the effect of IFR on the mechanical properties of PP composites was also evaluated and discussed.
The non-pillar entry (roadway) retained by roof cutting serves the two adjacent working faces. As compared with the conventional mining roadways, the roadway retained by roof cutting has a longer life cycle and receives more complicated influence from mining. Determining the location where the roof deformation and maximum deformation occur can provide an important basis for roadway support. Here, the direct roof of the roadway is studied by assuming it as an elastic deformation body. The stress features of the direct roof of the gob-side entry retained by roof cutting are analyzed, and the roof deformation is divided into five stages. The stress superposition principle is employed, and the equivalent concentrated load within the roadway is introduced. The mechanical model of the direct roof is established for the whole process of gob-side entry retaining by roof cutting. Next, the calculation formula for the concentration of direct roof at different positions is obtained for the whole process of gob-side entry retaining by roof cutting. The application scope of the calculation formula and the determination method of the key parameters are analyzed. The relationship between direct roof deformation of the roadway and stiffness of the support system is studied. The results show that the direct roof deformation has a symmetrical distribution about the midline. The maximum roof deformation occurs in the middle of the roadway, and it gradually decreases as the coal seam stiffness increases. During the example calculation, the maximum roof deformation is 280 mm for the gob-side entry retaining under primary mining. The measured maximum roof deformation is 320 m, and the error rate is 12.5%. It is then verified that the uniform mechanical model proposed in this study applies to the calculation of direct roof deformation in the gob-side entry retained by roof cutting.
The mechanical model of the basic roof fracture structure is established on the basis of key block theory to study the roof breaking mechanism of gob-side entry retaining under roof cutting and pressure relief, and the analytical formula of roof support resistance is derived when the key block of the basic roof is stable. The influence of roof cutting angle and cutting height on roof support resistance is also analyzed. Determining the cutting seam parameters of the retained roadway roof is necessary to identify the support resistance of the roadway roof due to the correlation between the roof cutting parameters and the support resistance. Taking the II 632 haulage drift of the Hengyuan coal mine as the engineering background, FLAC3D numerical simulation is used in this paper to analyze the influence of different roof cutting angles and cutting heights on the surrounding rock structure evolution of retained roadways. Results show that the roof cutting angle and cutting height respond to the support resistance of the retained roadway roof, and the support resistance required by the roof increases with the roof cutting angle and cutting height. This condition ensures that the side roof of the gob can be cut off smoothly, and the support resistance required by the roof of retained roadways is within a reasonable range. Through theoretical and numerical simulation analysis, the reasonable roof cutting height of II 632 haulage drift is 8 m and the roof cutting angle is 15°. The theoretical analysis and numerical simulation results reveal that the required support resistance to maintain the stability of the roadway roof is 0.38 MPa. The supporting scheme of the roof of the II 632 haulage drift in the Hengyuan coal mine is then designed. Finally, the field industrial test is used for verification. The borehole imaging results show that the overall line of the retained roadway roof is small based on the description of field monitoring results. The deformation of the surrounding rock surface of the retained roadway is less than 100 mm, and the roadway is 40 m from the lagging working face. The deformation rate of surrounding rock decreases with the increase in distance from the working face. The integrity of the retained roadway roof is good, and the deformation of the surrounding rock is effectively controlled.
An overlying rock structure plays a key role in controlling the roof deformation of nonpillar gob-side entry retaining by roof cutting. On the bases of the actual geological conditions of II 632 Haulage Roadway at the Hengyuan coal mine, a similar three-dimensional simulation experiment of roof precutting is conducted. Thereafter, the caving characteristics and migration law of the roof strata in the strike and dip directions are obtained. Moreover, the roof of the retained roadway and key strata of the goaf can form a hinge structure of the key blocks. By monitoring the deformation of the surrounding rock and stress distribution of the roof, the skew deformation characteristics of roadway roof are obtained. By observing the borehole peeping technology, the roof subsidence near the goaf is determined to be greater than that of the solid coal side, and the roof subsidence of the gob-side entry retained by roof cutting is greater than that of the floor heave and two sides approaching. Results of the three-dimensional similar simulation experiment indicate that the mechanical structure model of the key block of the retained roadway roof is constructed, and the mechanical analytical solution of the required support resistance of the retained roadway roof is obtained. This study proposes the constant resistance and large deformation anchor cable reinforcement support method to control the roof deformation of the retaining roadway. Through engineering application, the maximum value of the roof and floor movement of the retained roadway is stable at approximately 650 mm. The retained roadway can meet the demand of the next mining face.
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