Traditional polyamide-based interfacial polymerized nanofiltration (NF) membranes exhibit upper bound features between water permeance and salt selectivity. Breaking the limits of the permeability and rejections of these composite NF membranes are highly desirable for water desalination. Herein, a high-performance NF membrane (TFC-P) was fabricated via interfacial polymerization on the poly­(vinyl alcohol) (PVA) interlayered poly­(ether sulfone) (PES) ultrafiltration support. Owing to the large surface area, great hydrophilicity, and high porosity of the PES–PVA support, a highly cross-linked polyamide separating layer was formed with a thickness of 9.6 nm, which was almost 90% thinner than that of the control membrane (TFC-C). In addition, the TFC-P possessed lower ζ-potential, smaller pore size, and greater surface area compared to that of the TFC-C, achieving an ultrahigh water permeance of 31.4 L m–2 h–1 bar–1 and a 99.4% Na2SO4 rejection. Importantly, the PVA interlayer strategy was further applied to a pilot NF production line and the fabricated membranes presented stable water flux and salt rejections as comparable to the lab-scaled membranes. The outstanding properties of the PVA-interlayered NF membranes highlight the feasibility of the fabrication method for practical applications, which provides a new avenue to develop robust polyamide-based NF desalination membranes for environmental water treatment.

A high-performance nanofiltration (NF) membrane with simultaneously improved desalination and antifouling properties while maintaining regeneration ability is highly desirable in water treatment. Surface modification is an effective approach to enhance the performance of NF membranes. In the present study, a multifunctional thin-film composite NF membrane (Fe–TFC) was fabricated via coating a regenerable ferric ion–tannic acid (FeIII–TA) layer on the nascent polyamide membrane surface. The Fe–TFC membrane exhibited enhanced hydrophilicity, smaller pore size, and lower negative charge compared with the control membrane. The salt rejections and selectivity of divalent to monovalent ions were greatly improved with only a slight decrease in water permeability due to the presence of the coating layer. Meanwhile, dynamic fouling tests with humic acid demonstrated that the Fe–TFC membrane possessed an enhanced antifouling property and excellent flux recovery rate. After coating, the normalized water flux and flux recovery of the Fe–TFC membrane increased from 0.02 to 0.26 and 32.1 to 76.4% at the end of five cycles of fouling tests, respectively. In addition, the resultant membrane exhibited excellent durability and stability under harsh conditions for ∼10 days. Interestingly, the fouled coating layer can be easily removed by HCl cleaning and regenerated through an in situ strategy. Consequently, the regenerated membranes presented stable antifouling properties and desalination performance after several times of regeneration. It was demonstrated that the unique feature of FeIII–TA networks enables the coating layer to act as a protective layer for the underlying polyamide membrane, leading to the high performance of the composite membrane. This study provides a new insight for surface functionalization and easy regeneration of the TFC nanofiltration membrane in water treatment technology.

The demand for thin-film composite (TFC) nanofiltration membranes with superior permeance and high rejection is gradually increasing for seawater desalination and brackish water softening. However, improving the membrane permeance remains a great challenge due to the formation of excrescent polyamide in the substrate pores and thick polyamide film. Herein, we fabricated a highperformance TFC nanofiltration membrane via a classical interfacial polymerization reaction on a two-dimensional lamellar layer of transition-metal carbides (MXene). The MXene layer promoted the absorption of the reactive monomer, and higher amine monomer concentration facilitated the self-sealing and self-termination of interfacial polymerization to generate a thinner outer polyamide film from 68 to 20 nm. The almost nonporous lamellar interface inhibited the formation of inner polyamide in the substrate pores. In addition, the MXene lamellar layer could be eliminated by mild oxidation after interfacial polymerization to avoid imparted additional hydraulic resistance. The resulting TFC membrane conferred a high rejection above 96% for Na 2 SO 4 and excellent permeance of 45.7 L•m −2 •h −1 •bar −1 , which was almost 4.5 times higher than that of the control membrane (10.2 L•m −2 •h −1 •bar −1 ). This research provides a feasible strategy for fabricating a high-performance nanofiltration membrane using two-dimensional nanosheets as a templated interface.

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An ordered mesoporous perovskite, La2CoMnO6−δ (MLCMO), was synthesized for the first time using a facile method of evaporation-induced self-assembly. The N2-sorption, scanning electron microscopy, and transmission electron microscopy measurements indicated that the optimized MLCMO possessed a high specific surface area (58.7 m2/g) and was uniformly mesoporous (11.6 nm). The MLCMO exhibited superior catalytic performance in peroxymonosulfate (PMS) activation for atrazine (ATZ) degradation. From a comparison view, the catalytic activity of the mesoporous MLCMO outperformed that of the bulk La2CoMnO6−δ (LCMO) and other common PMS activators, including α-MnO2, Co3O4, and CoFe2O4. The mechanisms of PMS activation by the MLCMO were investigated by X-ray photoelectron spectroscopy, electron spin resonance, and quenching tests. SO4 •–, •OH, 1O2, and O2 •– were identified as main reactive oxygen species generated from PMS activation. The Co and Mn in MLCMO were the active sites responsible for active radical generation. The lattice oxygen reversible redox sites (OL –/OL 2–), which were involved in the electron transfer of the MnIII/MnIV cycle, were demonstrated as redox partners to the cation active sites. In addition, the SO4 •–/•OH radical conversion was promoted at pH 11, which accelerated the consumption of PMS and seriously inhibited the degradation of ATZ.

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