We have reported the enhanced field emission properties of quasialigned 3C-SiC nanowires synthesized via catalyst assisted pyrolysis of polysilazane. The as-synthesized Al-doped SiC nanowires possess a tapered and bamboo-like structure with clear and tiny tips sized in several to tens of nanometers. The fabricated SiC nanowires have extremely low turn-on fields of 0.55−1.54 V μm−1 with an average of ∼1 V μm−1, which is the lowest one ever reported for any type of SiC emitters. The field-enhancement factor has been calculated to be 2983. The superior FE properties can be clearly attributed to the significant enhancements of the tapered and bamboo-like unique morphology and Al doping of SiC nanowires. Density functional theory calculations suggest that Al dopants in 3C-SiC nanowires could favor a more localized state near the Fermi energy, which improves the electron field emissions. We strongly believe that the present work will open a new insight in the fabrication of field emission sources with ultralow turn-on fields enhanced by both shape and doping.
The current trend with integrated energy-storage units in portable electronics lies in continuous advancements in nanostructured materials, thin-film manufacture technologies, and device architectures with enhanced functionality and reliability of existing components. Despite this, it is still challenging to provide cost-efficient solution to further improve the energy and power densities and cyclability of supercapacitors (SCs), especially at ultrafast rates while maintaining their environmentally friendly and even well-run at arbitrary harsh environments character. In this contribution, we report the fabrication of quasi-aligned single crystalline 3C-SiC nanowire (3C-SiCNW) array with tailored shapes and nitrogen-doping (N-doping). The resultant large-scale SiCNWs were directly grown on the surface of a flexible carbon fabric via a simple chemical vapor deposition method. We found that the SC performance of SiCNW arrays can be substantially enhanced by nitrogen doping, which could favor a more localized impurity state near the conduction band edge that greatly improves the quantum capacitance and hence increases the bulk capacitance and the high-power capability. The measured areal capacitances are higher with values of 4.8 and 4.7 mF cm(-2), in aqueous and gel electrolytes, respectively. The all-solid-state flexible textile-based SCs (TSCs) made with these electrodes are mechanically robust under bent and twisted states. Further, they show a power density of 72.3 mW cm(-2) that is higher than that of electrolytic capacitors, and an energy density of 1.2 × 10(-4) mW·h cm(-2), in association with superior rate ability, cyclability, and being environmentally friendly. Such SiCNW-TSC devices allow for operations at ultrahigh rate up to 30 V s(-1), 2 orders of magnitude higher than that of conventional supercapacitors. All these data are comparable to the reported results for 1D nanostructure-based carbon nanotubes (CNTs) or graphenes, thus showing the promising application as large-area flexible textile electronics.
We report for the first time the fabrication of p-type SiC nanowire field-effect transistors (FETs) using an individual Al-doped 3C-SiC nanowire with a single crystalline structure. The Raman spectroscopy of the as-grown p-type wire indicates that the linewidth and peak intensity of LO-phonon bands are sensitive to temperature variations.
Previous research has indicated that, compared to audio-only presentation, audio-visual congruent presentation can lead to a more intense emotional response. In the present study, we investigated the audio-visual integration effect on emotions elicited by positive or negative music and the role of visual information presentation durations. The participants were presented with audio-only condition, audio-visual congruent condition, and audio-visual incongruent condition and then required to judge the intensity of emotional experience elicited by the music. Their emotional responses to the music were measured using self-ratings and physiological aspects, including heart rate, skin temperature, EMG root mean square and prefrontal EEG. Relative to the audio-only presentation, the audio-visual congruent presentation led to a more intense emotional response. More importantly, the audio-visual integration occurred both in the positive music and in the negative music. Furthermore, the audio-visual integration effect was larger for positive music than for negative music; meanwhile the audio-visual integration effect was strongest with the visual information presented within 80s for negative music, which indicated that this integration effect was more likely to occur in the negative music. These results suggest that when the music was positive, the effect of audio-visual integration was greater. When the music was negative, the modulation effect of the presentation durations of visual information on the music-induced emotion was more significant.
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