Development of efficient and robust electrocatalysts is critical for practical fuel cells. We report one-dimensional bunched platinum-nickel (Pt-Ni) alloy nanocages with a Pt-skin structure for the oxygen reduction reaction that display high mass activity (3.52 amperes per milligram platinum) and specific activity (5.16 milliamperes per square centimeter platinum), or nearly 17 and 14 times higher as compared with a commercial platinum on carbon (Pt/C) catalyst. The catalyst exhibits high stability with negligible activity decay after 50,000 cycles. Both the experimental results and theoretical calculations reveal the existence of fewer strongly bonded platinum-oxygen (Pt-O) sites induced by the strain and ligand effects. Moreover, the fuel cell assembled by this catalyst delivers a current density of 1.5 amperes per square centimeter at 0.6 volts and can operate steadily for at least 180 hours.
The exploration of highly active, durable, and cost-effective electrocatalysts for the oxygen reduction reaction (ORR) is indispensable for several important energy conversion technologies. Significant achievements have been made with numerous efforts devoted by the academic and industrial researchers. In this review, from a more practical point of view, the tests and experiments at the membrane electrode assembly (MEA) level are accentuated due to the fact that the rotating disk electrode (RDE) level performance cannot be transformed directly into the MEA level. Four major categories of the current ORR electrocatalysts are discussed, namely, platinum group metal (PGM or noble) catalysts, non-PGM catalysts, carbon-based catalysts, and single-atom-based catalysts. The advantages and shortcomings, along with the performance achieved by the catalysts, are briefly reviewed, and the improvement in the rational design approaches is emphasized at the full-cell level. Finally, the present challenges and prospects are discussed for developing advanced ORR electrocatalysts.
In this work, the effects of the addition of transition metals (Mn, Fe, Co, Ni, Cu) on the structure and performance of the doped carbon catalysts M-PANI/C-Mela are investigated. The results show that the doping of various transition metals affected structures and performances of the catalysts significantly. Doping with Fe and Mn leads to a catalyst with a graphene-like structure, and doping with Co, Ni, and Cu leads to a disordered or nanosheet structure. The doping of transition metals can enhance the performance of the catalysts, and their ORR activity follows the order of Fe > Co > Cu > Mn > Ni, which is consistent with the order of their active N contents. We suggest that the various performance enhancements of the transition metals may be the result of the joint effect of the following three aspects: the N content/active N content, metal residue, and the surface area and pore structure, but not the effect of any single factor.
The main challenges to the commercial viability of polymer electrolyte membrane fuel cells are (i) the high cost associated with using large amounts of Pt in fuel cell cathodes to compensate for the sluggish kinetics of the oxygen reduction reaction, (ii) catalyst degradation, and (iii) carbon-support corrosion. To address these obstacles, our group has focused on robust, carbon-free transition metal nitride materials with low Pt content that exhibit tunable physical and catalytic properties. Here, we report on the high performance of a novel catalyst with low Pt content, prepared by placing several layers of Pt atoms on nanoparticles of titanium nickel binary nitride. For the ORR, the catalyst exhibited a more than 400% and 200% increase in mass activity and specific activity, respectively, compared with the commercial Pt/C catalyst. It also showed excellent stability/durability, experiencing only a slight performance loss after 10,000 potential cycles, while TEM results showed its structure had remained intact. The catalyst's outstanding performance may have resulted from the ultrahigh dispersion of Pt (several atomic layers coated on the nitride nanoparticles), and the excellent stability/durability may have been due to the good stability of nitride and synergetic effects between ultrathin Pt layer and the robust TiNiN support.
Atomically ultrathin rhodium nanosheets obtained by the cyanogel reduction method demonstrate an excellent electrocatalytic activity for the nitrogen reduction reaction.
Conspectus Fuel cells are among the cutting-edge energy technologies. Their commercial development is still hindered by noble platinum (Pt) catalysts for the oxygen reduction reaction (ORR) at the cathode, which not only determine the energy conversion efficiency and service life but also are closely related to the cost and broad application of fuel cells. Given the bright and enormous future of fuel cells, ORR catalysts should possess highly efficient performance yet meet the acceptable Pt costs for large-scale application. Extensive efforts are concentrated on the optimization of Pt-based nanostructures and upgradation of functional carriers to achieve the low-cost and high-activity Pt-based catalysts. By improving the Pt utilization and accessible surface, reducing Pt consumption and catalyst costs, accelerating mass exchange and electron transfer, alleviating the corrosion and agglomeration of carriers and Pt, accompanying with the assistance of robust yet effective functional supports, the service level and life of Pt-based electrocatalysts would be significantly improved and fuel cells could get into commercial market covering broader applications. In this Account, we focus on the recent development of Pt-based catalysts to figure out the problems associated with ORR catalysts in fuel cells. Recent development of Pt-based catalysts is discussed in different stages: (1) multiscale development of Pt-based nanostructures; (2) multielement regulation over Pt-based alloy composition; (3) upgradation of carbon and noncarbon support architectures; (4) development of integrated Pt-based catalysts for fuel cells. Finally, we propose some future issues (such as reaction mechanism, dynamic evolutions, and structure–activity relationship) for Pt-based catalysts, which mainly involve the preparation strategy of Pt-integrated catalysts (combination of Pt nanostructures with nanocarbons), performance evaluation (standard measurement protocols, laboratory-level rotating disk electrode (RDE) measurements, application-level membrane electrode assembly (MEA) service test), advanced interpretation techniques (spectroscopy, electron microscopy, and in situ monitoring), and cutting-edge simulation/calculations and artificial intelligence (simulation, calculations, machine learning, big data screening). This Account calls for the comprehensive development of multiscale, multicomponent, and high-entropy Pt-based alloy nanostructures, and novel and stable carriers, which provide more available options for rational design of low-cost and high-performance Pt-integrated ORR catalysts. More importantly, it will give an in-depth understanding of the reaction mechanism, dynamic development, and structure–performance relationship for Pt-based catalysts in fuel cells and related energy technologies.
The investigation of highly effective, durable, and cost-effective electrocatalysts for the hydrogen evolution reaction (HER) is a prerequisite for the upcoming hydrogen energy society. To establish a new hydrogen energy system and gradually replace the traditional fossil-based energy, electrochemical water-splitting is considered the most promising, environmentally friendly, and efficient way to produce pure hydrogen. Compared with the commonly used platinum (Pt)-based catalysts, ruthenium (Ru) is expected to be a good alternative because of its similar hydrogen bonding energy, lower water decomposition barrier, and considerably lower price. Analyzing and revealing the HER mechanisms, as well as identifying a rational design of Ru-based HER catalysts with desirable activity and stability is indispensable. In this review, the research progress on HER electrocatalysts and the relevant describing parameters for HER performance are briefly introduced. Moreover, four major strategies to improve the performance of Ru-based electrocatalysts, including electronic effect modulation, support engineering, structure design, and maximum utilization (single atom) are discussed. Finally, the challenges, solutions and prospects are highlighted to prompt the practical applications of Ru-based electrocatalysts for HER.
In recent years, rechargeable Li-air and Zn-air batteries have attracted wide attention due to their high theoretical specific energy densities. However, the high cost and poor stability of noble metal catalysts for the oxygen redox reactions limit their practical large-scale application. On contrast, low-cost transition metal oxide (TMO)-based composite materials exhibit considerable bifunctional activity for oxygen reduction and oxygen evolution, and excellent stability, which holds great potential over the precious metal-based catalysts. This work briefly introduces the recent advances in TMO-based composites as bifunctional oxygen electrocatalysts for Li-air and Zn-air batteries. After a brief introduction into the research field of air batteries, metal oxides (including Co-and Mn-based oxides) and polymetallic oxides (mainly spinel and perovskite types) are reviewed. In consideration of the poor electronic conductivity of metal oxide catalysts, composites including additional conductive materials are also introduced. Finally, challenges and perspectives of bifunctional TMOs are emphasized to stimulate innovations for the future development of practical Li-air and Zn-air batteries.[a] Dr.
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