Summary Composite expended graphite (EG)/Ba(OH)2·8H2O form‐stable phase change material (PCM) is prepared with porous adsorption method in this study to solve the problem of the leakage risk in the application process based on barium hydroxide octahydrate. In addition, the thermal properties and stability have been measured and verified. Thermal conductivity of each group composite material was enhanced by about two to four times, while the addition has little negative effect on the other properties. With microscopic features being characterized by scanning electron microscope (SEM), the experimental result demonstrates that the composite material with 7 wt% of EG is optimal to be a saturated state between two phases. After the thermal cyclings of 100, 300, and 500 times, thermal properties did not change dramatically, which can be used as an ideal material for solar thermal storage system within finite thermal cyclings. In order to simulate the operating condition of solar energy or waste heat storage, the composite material was encapsulated in the heat storage unit with pipe bundle, and heat storage/release experiences were performed to test the performance of the material and hot water supply. The results indicate that the composite material is qualified to storage and release sufficient heat. The experimental data can provide necessary technical reference for engineering design and effect prediction in practical application.
Purpose Phase change energy storage is an important solution for overcoming human energy crisis. This study aims to present an evaluation for the thermal performances of a phase change material (PCM) and a PCM–metal foam composite. Effects of pore size, pore density, thermal conductivity of solid structure and mushy region on the thermal storage process are examined. Design/methodology/approach In this paper, temperature, flow field and solid–liquid interface of a PCM with or without porous media were theoretically assessed. The influences of basic parameters on the melting process were analyzed. A PCM thermal storage device with a metal foam composite is designed and a thermodynamic analysis for it is conducted. The optimal PCM temperature and the optimal HTF temperature in the metal foam-enhanced thermal storage device are derived. Findings The results show that the solid–liquid interface of pure PCM is a line area and that of the mixture PCM is a mushy area. The natural convection in the melting liquid is intensive for a PCM without porous medium. The porous medium weakens the natural convection and makes the temperature field, flow field and solid–liquid interface distribution more homogeneous. The metal foam can greatly improve the heat storage rate of a PCM. Originality/value Thermal storage rate of a PCM is compared with that of a PCM–metal foam composite. A thermal analysis is performed on the multi-layered parallel-plate thermal storage device with a PCM embedded in a highly conductive porous medium, and an optimal melting temperature is obtained with the exergy optimization. The heat transfer enhancement with metal foams proved to be necessary for the thermal storage application.
Purpose A combination of highly conductive porous media and nanofluids is an efficient way for improving thermal performance of relevant applications. For precisely predicting the flow and thermal transport of nanofluids in porous media, the purpose of this paper is to explore the inter-phase coupling numerical methods. Design/methodology/approach Based on the lattice Boltzmann (LB) method, this study combines the convective flow, non-equilibrium thermal transport and phase interactions of nanofluids in porous matrix and proposes a new multi-phase LB model. The micro-scale momentum and heat interactions are especially analyzed for nanoparticles, base fluid and solid matrix. A set of three-phase LB equations for the flow/thermal coupling of base fluid, nanoparticles and solid matrix is established. Findings Distributions of nanoparticles, velocities for nanoparticles and the base fluid, temperatures for three phases and interaction forces are analyzed in detail. Influences of parameters on the nanofluid convection in the porous matrix are examined. Thermal resistance of nanofluid convective transport in porous structures are comprehensively discussed with the models of multi-phases. Results show that the Rayleigh number and the Darcy number have significant influences on the convective characteristics. The result with the three-phase model is mildly larger than that with the local thermal non-equilibrium model. Originality/value This paper first creates the multi-phase theoretical model for the complex coupling process of nanofluids in porous structures, which is useful for researchers and technicians in fields of thermal science and computational fluid dynamics.
In order to solve undercooling and phase separation of sodium acetate trihydrate (SAT), experimental screening method was used to select nucleating agents and thickeners that are suitable for SAT, and the optimal ratio was identified. Through screening experiments of nucleating agents, it is found that disodium hydrogen phosphate can be used as an effective nucleating agent for SAT. When the weight content of disodium hydrogen phosphate in SAT is 2%, the degree of undercooling was reduced to approximately 2 K. The addition of 1–1.5% (weight) of xanthan gum (XG) to SAT can effectively inhibit the phase separation. Since the properties of SAT changes after the modification, the corresponding comparison analysis was performed. The results showed that XG has a significant influence on the SAT performance of SAT. With the addition of 1.5 wt % of XG in pure SAT, the latent heat of fusion and solid/liquid volume expansion reduce by 5.2% and 5.4% respectively, and the thermal conductivity and solid/liquid density also decreases accordingly.
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