In order to explore the spatial pesticide spraying deposition distribution, the downwash flow field characteristics for unmanned aerial vehicle (UAV) pesticide application with accurate flight height and velocity and the relationship of these two aspects, a novel measurement method was proposed in this paper. A model '3WQF80-10' single-rotor diesel UAV was tested using this method in wheat field and the effects of flight direction, flight parameters and crosswind on the distribution of spatial spraying deposition quality balance (SSDQB) and the downwash flow field distribution were researched. A cuboid aluminum sampling frame of spatial spraying deposition quality balance (SFSSDQB) with monofilament wires was made for collecting the droplets in four directions, and a set of multi-channel micro-meteorology measurement system (MMMS) was applied for measuring the downwash wind speed in three directions. Besides, BeiDou Navigation Satellite System (BNSS) was used for controlling and recording the working height, velocity and track of this model of single-rotor UAV. The results showed the distribution of the spatial spray deposition and the downwash flow field of UAV could be measured effectively at exact flight height and velocity via this method. When the average wind speed was 0.9 m/s, the average temperature was 31.5°C and the average relative humidity was 34.1%, and the average distribution ratios of spraying deposition for model '3WQF80-10' UAV on the upwind part, the top part, the downwind part and the bottom part were 4.4%, 2.3%, 50.4% and 43.7%, respectively. The flight directions of forward and backward had an impact on droplet deposition distribution and the working effect of flying backwards, with 60% of deposition ratio of the bottom part of the SFSSDQB, was better than flying forward. There was a linear negative correlation between the coefficient of variation (CV) of the bottom part and the flight height and the coefficient of determination was 0.9178, which means that the deposition distribution becomes more uniform with the increase of height. Additionally, there was a linear positive correlation between weighted mean deposition rate and crosswind speed and the coefficient of determination was 0.9684, which shows the deposition distribution gets more concentrated towards the downwind part with the rise of crosswind speed. Therefore, according to the results of tests of downwash airflow speed, it is shown that regardless of the flight direction and height and the crosswind, all these factors influence the droplet deposition distribution via weakening the intensity of the downwash airflow field in the direction perpendicular to the ground. The results can provide valuable information for the research of UAV pesticide application techniques and the establishment of the standard of spraying deposition and drift tests of UAV in crop field.

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The reduction of pesticide aerial spraying drift is still one of the major challenges in modern agriculture. The aim of this study was to evaluate the drift potential of different types of unmanned aerial vehicle (UAV) and adjuvant products for reducing spray drift in aerial applications. Three types of UAV (3WQF120-12 and 3CD-15 fuel oil powered single-rotor UAV and HY-B-15L battery powered single-rotor UAV) were selected in this study with regular application parameters to compare each spray drift, and 3WQF120-12 fuel oil powered UAV was selected to quantify spray drift of 6 adjuvants dissolved in water under field conditions. Solutions were marked with brillant sulfoflavin dye (BSF) at 0.1%. Petri dishes and rotary impactors were used to collect airborne and sediment drift, respectively. Drift deposits were evaluated by spectrophotometry in order to quantify deposits. The results showed that when the flight height was 1.5-2.0 m above the crop at the flight speed of 4-5 m/s and the average wind speed of 1.63-1.73 m/s, 3WQF120-12 fuel oil powered UAV had lower drift potential than the other two types; D V0.5 and percentage of droplets with diameter ≤75 μm had very significant effects on spray drift percentage (p=0.01); the risk of drift in agricultural spraying could be significantly decreased not only by reducing the percentage of fine droplets but also by changing droplet spectra. Compared to water, Silwet DRS-60, ASFA+B, T1602, Break-thru Vibrant, QF-LY and Tmax could reduce by 65%, 62%, 59%, 46%, 42%, and 19% spray drift, respectively. when water without adjuvants were sprayed, 90% of drift droplets were located within a range of 10.1 m of the target area while with 0.8% Silwet DRS-60 adjuvant in water, the distance was shortened to 6.4 m.

Novel molecularly imprinted polymers (MIPs) based on the technique of surface-enhanced Raman scattering (SERS) were successfully prepared. Firstly, ZnO nanorods were fabricated with Ag by reduction of Ag on the surface of the ZnO nanorods. Then, ZnO/Ag heterostructures were used as the substrate, rhodamine 6G was used as the template molecule, acrylamide was used as the functional monomer, ethylene glycol dimethacrylate was used as the cross-linker, and 2,2'-azobis(2-methylpropionitrile) was used as the initiator to prepare the ZnO/Ag MIPs (ZOA-MIPs). Through characterization analysis, it was proved that the novel ZOA-MIPs exhibited excellent SERS properties and selectivity. Under the optimal conditions, there was a good linear relationship (R = 0.996) between the Raman signal (at 1654 cm) and the concentration of the templates, and the detection limit was 10 mol L. It was also proved that the ZOA-MIPs had the property of self-cleaning, resulting in good reusability. It is envisaged that the sensitivity of SERS coupled with the selectivity of MIPs could result in a promising chemosensor for practical applications.

The essence of cutting carbon fibre-reinforced plastic (CFRP) composites is a process of material failure and chip formation. The mechanism of cutting CFRPs can be explained from the perspective of local removal of material on the microscopic level. The morphology of the chips resulting from the cutting process can be determined from the perspective of the overall failure of the material on the macroscopic level. To reveal the mechanism of cutting CFRPs at both levels, a macroscopic model and a microscopic model are established in this study. Orthogonal cutting is applied in both of the models to illuminate the removal process. Combined with experimental observations, the results that obtained from both the macroscopic and microscopic level revealed the different mechanics of cutting CFRPs for different fibre orientations. For example, the forms of fracture that occur at 0° fibre orientation are primary interface cracking and fibre bending; the resulting chips have long shapes.

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A new method is described for the determination of the pesticide λ-cyhalothrin (LC). It combines SERS detection with molecular imprinting and largely improves selectivity. A multilayer surface imprinted nanocomposite was synthesized in two steps on a nanostructure of type SiO@rGO@Ag acting as a substrates. Firstly, the surface of the SiO@rGO@Ag composite was modified with self-polymerized dopamine. Secondly, surface-initiated polymerization was carried out to prepare a molecularly imprinted polymer (MIP) using LC as the template. The use of this SiO@rGO@Ag-MIP allows for excellent SERS based detection and has high selectivity for LC. The Raman intensity and LC concentration present perfect linear relationship between 10 to 10 mol L and the detection limit is 3.8×10 mol L. All the procedures are conducted in aqueous or ethanol solution. Graphical abstract Schematic of a new method for determination of the pesticide λ-cyhalothrin. It combines SERS detection with molecular imprinting and largely improves selectivity. A multilayer surface imprinted nanocomposite was synthesized in two steps on a nanostructure of type SiO@rGO@Ag acting as a substrates.

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