Three-dimensional nanofibrous aerogels (NFAs) that are both highly compressible and resilient would have broad technological implications for areas ranging from electrical devices and bioengineering to damping materials; however, creating such NFAs has proven extremely challenging. Here we report a novel strategy to create fibrous, isotropically bonded elastic reconstructed (FIBER) NFAs with a hierarchical cellular structure and superelasticity by combining electrospun nanofibres and the fibrous freeze-shaping technique. Our approach causes the intrinsically lamellar deposited electrospun nanofibres to assemble into elastic bulk aerogels with tunable densities and desirable shapes on a large scale. The resulting FIBER NFAs exhibit densities of 40.12 mg cm À 3 , rapid recovery from deformation, efficient energy absorption and multifunctionality in terms of the combination of thermal insulation, sound absorption, emulsion separation and elasticity-responsive electric conduction. The successful synthesis of such fascinating materials may provide new insights into the design and development of multifunctional NFAs for various applications.
Creating an efficient, cost-effective method that can provide simple, practical and high-throughput separation of oil-water mixtures has proved extremely challenging. This work responds to these challenges by designing, fabricating and evaluating a novel fluorinated polybenzoxazine (F-PBZ) modified nanofibrous membrane optimized to achieve gravity driven oil-water separation. The membrane design is then realized by a facile combination of electrospun poly(m-phenylene isophthalamide) (PMIA) nanofibers and an in situ polymerized F-PBZ functional layer incorporating SiO2 nanoparticles (SiO2 NPs). By employing the F-PBZ/SiO2 NP modification, the pristine hydrophilic PMIA nanofibrous membranes are endowed with promising superhydrophobicity with a water contact angle of 161° and superoleophilicity with an oil contact angle of 0°. This new membrane shows high thermal stability (350 °C) and good repellency to hot water (80 °C), and achieves an excellent mechanical strength of 40.8 MPa. Furthermore, the as-prepared membranes exhibited fast and efficient separation of oil-water mixtures by a solely gravity driven process, which makes them good candidates for industrial oil-polluted water treatments and oil spill cleanup, and also provided new insights into the design and development of functional nanofibrous membranes through F-PBZ modification.
Novel flexible, mesoporous, and magnetic γ-Fe2O3@SiO2 nanofibrous membranes with high γ-Fe2O3 content and uniform distribution were prepared by a facile in situ growth method, which exhibit prominent mechanical strength and magnetic responsive performance, as well as efficient adsorption for organics in water.
Quaternized polymers are critical components for various
energy
devices. Vinyl-addition polynorbornenes provide high mechanical strength,
high ion conductivity, and chemical stability in a wide range of pH
environments due to the all-C–C bond backbone. Herein, we present
the synthesis of a series of quaternized polynorbornene random copolymers
via vinyl addition polymerization and elucidate the impact of polymer
composition on their properties. The quaternary ammonium alkyl tether
length and the ratio of n-hexylnorbornene to unsubstituted
norbornene are systemically tailored. A copolymer of 5-(3-bromopropyl)-2-norbornene
and norbornene with pendant trimethylammonium groups achieved hydroxide
conductivity of 109 mS/cm at 80 °C with a modest water uptake
of 72%. The addition of n-hexylnorbornene to the
copolymer, to make a terpolymer, allows for the polymer composition
to be tailored for properties, including a decrease in water uptake
and higher processability, despite a slightly decreased hydroxide
conductivity. Moreover, the developed membranes are chemically robust
and highly mechanically stable, enabling thin membranes to be easily
fabricated. This study provides insight into important design parameters
for quaternized polynorbornenes for a variety of energy storage and
conversion devices, especially fuel cells.
We
report that hot stretching of poly(ethylene oxide) (PEO)-based
solid polymer electrolytes (SPEs) can lead to a preferred orientation
of PEO crystalline lamellae, thereby reducing the tortuosity of the
ion-conduction pathway along the thickness direction of the SPE film,
causing improved ionic conductivity. The hot stretching method is
implemented by stretching SPE films above the melting point of PEO
in an inert environment followed by crystallization at room temperature
while maintaining the applied strain. The effect of hot stretching
on the crystalline orientation, crystallinity, morphology, and ion
transport in PEO with two types of salts, lithium bis(trifluoromethanesulfonyl)imide
(LiTFSI) and lithium triflate (LiCF3SO3), is
investigated in detail. Wide-angle X-ray scattering (WAXS) and small-angle
X-ray scattering (SAXS) show that the orientation of PEO crystalline
lamellae induces the formation of a short ion-conduction pathway along
the through-plane direction of the SPE films, leading to 1.4- to 3.5-fold
enhancement in the through-plane ionic conductivity.
Self-assembled mechanically robust Dopa-bearing triblock copolymer networks improve underwater adhesion through both energy dissipation and interfacial bonding. Polymer networks that incorporate energy dissipating motifs could improve the performance of high-performance wet adhesives rather than only by interfacial bonds.
Bridging the gap between academia and industry in plastic recycling will accelerate innovation and deployment toward solving the global challenge of plastic waste management and establishing net zero carbon society.
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