The risk of P leaching from topsoil based on the change‐point estimated via a split‐line model between Olsen P and leachable P extracted by 0.01 M CaCl2 has been reported. However, little information is available for the assessment of P leaching from soil profiles. In this study, samples were collected at three depth profiles (0–20 cm, topsoil; 20–40 cm, subsoil; 40–60 cm, third‐layer soil) at each of 74 sites under agriculture and forest in an agroforestry area. A cascade extraction method was proposed to determine the leachable P in the subsoil, extracted by the topsoil extraction solution; a similar extracted process was followed in the third‐layer soil, and in the topsoil, it was still extracted by 0.01 M CaCl2. A positive linear correlation was found between the subsoil leachable P extracted by the topsoil extraction solution and the accumulated P obtained from the subsoil leached by topsoil leachates, and so on. Therefore, the cascade extraction method for determining leachable P from topsoils and underlying soils could be valuable for predicting the potential of P leaching from soil profiles. Approximately 81, 73, and 73% of the agricultural sampling sites were at or above the change‐points for the soil depths of 0 to 20, 20 to 40, and 40 to 60 cm (30.4, 32.9, and 18.2 mg kg−1 respectively); these values were higher than those for the forest site, implying a high risk of P leaching from agricultural soil profiles in the study area.
Core Ideas
A cascade extraction method for evaluating P leaching from soil profiles was proposed.
The correlation of soil leachable P and accumulated P in soil leachates was confirmed.
The risk of P leaching from soil profiles in an agroforestry area was calculated.
For the purpose of elucidating the environmental characteristics of anion surfactants [linear alkylbenzene sulfonates (LAS)] in the water of Lake Dianchi, a sampling investigation in the field from October 2006 to July 2007 and a batch of biodegradation experiments in the laboratory were carried out. The results showed that concentrations of LAS ranged from 18.6 to 260.1 μg L −1 , and the average concentration was 52.6 μg L −1 in Lake Dianchi. The highest concentrations of LAS were found in the Northwest region, and the distribution of LAS varied through seasons, with much lower concentrations in fall than in any other seasons. LAS can be primarily biodegraded by microorganisms in the lake water, and the per- centage of degradation was >97% after 28 days. Biodegradation of LAS was well-fitted with the kinetic model presented in this paper, and the half-lives ranged from 3.2 to 16.3 days. Temperature, pH, and initial concentrations could affect the biodegradation of LAS, among which temperature was the major factor influencing on biodegradation of LAS in water of Lake Dianchi.
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