Rechargeable Zn‐MnO2 batteries are boosted by the reversible intercalation reactions in mild aqueous electrolytes, but they still suffer from cathode degradation. Herein, Zn‐MnO2 batteries with high durability and high energy density are achieved by supplementing MnO2 deposition and dissolution in a mild aqueous electrolyte. The main finding is that adjusting Mn2+ concentration to a critical range enables a reversible MnO2/Mn2+ redox conversion without the involvement of oxygen evolution. This can recycle the by‐products from MnOOH disproportionation (MnOOH → MnO2 + Mn2+), resulting in a battery with extremely high durability (16 000 cycles without obvious capacity fading), high energy density (602 Wh kg−1 based on the active mass of the cathode), and high‐rate capacity (430 mAh g−1 at 19.5 A g−1). The utilization of a 3D carbon nanotube foam skeleton can accommodate the volume change during MnO2 deposition/dissolution and provide paths for efficient charge and mass transport. This work provides a feasible way to push the development of Zn‐MnO2 batteries in mild aqueous electrolytes.
Confining Zn plating and stripping in a robust and conductive 3D carbon nanotube network results in an electrode, which shows excellent reversibility at high depth of discharge and enables zinc-ion batteries with high-rate and long-term performance.
To address the lack of a suitable electrolyte that supports the stable operation of the electrochemical yarn muscles in air, an ionic‐liquid‐in‐nanofibers sheathed carbon nanotube (CNT) yarn muscle is prepared. The nanofibers serve as a separator to avoid the short‐circuiting of the yarns and a reservoir for ionic liquid. The ionic‐liquid‐in‐nanofiber‐sheathed yarn muscles are strong, providing an isometric stress of 10.8 MPa (about 31 times the skeletal muscles). The yarn muscles are highly robust, which can reversibly contract stably at such conditions as being knotted, wide‐range humidity (30 to 90 RH%) and temperature (25 to 70 °C), and long‐term cycling and storage in air. By utilizing the accumulated isometric stress, the yarn muscles achieve a high contraction rate of 36.3% s−1. The yarn muscles are tightly bundled to lift heavy weights and grasp objects. These unique features can make the strong and robust yarn muscles as a desirable actuation component for robotic devices.
The
contraction behavior of spider dragline silk upon water exposure
has drawn particular interest in developing humidity-responsive smart
materials. We report herein that the spider dragline silk yarns with
moderate twists can generate much improved lengthwise contraction
of 60% or an isometric stress of 11 MPa when wetted by water. Upon
the removal of the absorbed water, the dried and contracted spider
silk yarns showed programmable contractile actuations. These yarns
can be plastically stretched to any specified lengths between the
fully contracted state and the state before supercontraction and return
to the fully contracted state when wetted. Moreover, the generated
isometric stress of these yarns is also programmable, depending on
the stretching ratio. The mechanism of the programmable reversible
contraction is based on the plastic mechanical property of the dried
and contracted spider silk yarns, which can be explained by the variation
of the hydrogen bonds and the secondary structures of the proteins
in spider dragline silk. Humidity alarm switches, smart doors, and
wound healing devices based on the programmable contractile actuations
of the spider silk yarns were demonstrated, which provide application
scenarios for the supercontraction of spider dragline silk.
Catalysts that boost oxygen reduction reaction (ORR) are highly needed for fuel cells and metal-air batteries. Herein, we report the preparation of surface-vacancy-rich PtFe interconnected nanowires as an excellent ORR...
Summary
Improved diagnostic reagents would be of considerable benefit in enhancing the specificity and sensitivity of rapid assays for Burkholderia pseudomallei, the causative agent of melioidosis. The purpose of this work is to develop aptamers, high affinity RNA-based molecular recognition molecules, which could be used as reagents for identification whole organism in assays of biological samples. Data are presented demonstrating the purification of recombinant B. pseudomallei secreted or surface-exposed macromolecules, which have been expressed in Escherichia coli, and the initial stages of aptamer generation using these recombinant proteins. Future studies will focus upon the expansion of this methodology to include other target macromolecules located on or near the outer membrane of this organism.
In this work, we demonstrate the immunocapture and on-line fluorescence immunoassay of protein and virus based on porous polymer monoliths (PPM) in microfluidic devices. Poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate) [poly(GMA-co-EGDMA)] monoliths were successfully synthesized in the polydimethylsiloxane (PDMS) microfluidic channels by in situ UV-initiated free radical polymerization. After surface modification, PPM provides a high-surface area and specific affinity 3D substrate for immunoassays. Combining with well controlled microfluidic devices, the direct immunoassay of IgG and sandwich immunoassay of inactivated H1N1 influenza virus using 5 μL sample has been accomplished, with detection limits of 4 ng mL(-1) and less than 10 pg mL(-1), respectively. The enhanced detection sensitivity is due to both high surface area of PPM and flow-through design. The detection time was obviously decreased mainly due to the shortened diffusion distance and improved convective mass transfer inside the monolith, which accelerates the reaction kinetics between antigen and antibody. This work provides a novel microfluidic immunoassay platform with high efficiency thereby enabling fast and sensitive immunoassay.
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