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To investigate the enhanced oil recovery (EOR) technology by chemical flooding in an edge water reservoir, a 3D physical simulation experimental device for the edge water reservoir was developed, and polymer/surfactant binary flooding experiments were carried out under different edge water energies. In addition, the effect and mechanism of binary flooding on EOR under different edge water energies were comprehensively analyzed. Experimental results show that edge water intrusion considerably affects EOR by binary flooding. The stronger the edge water energy, the worse the effect of EOR by binary flooding. Edge water possibly diluted the concentration of the chemical agent medium that is injected into the reservoir, and the degree of dilution varied in different regions. The dilution region was mainly distributed between the injection wells and edge water. The stronger the edge water energy, the higher the dilution multiple of chemical agent and the greater the recovery loss rate by binary flooding.

Experimental studies on biogas yield of Ulva pertusa were carried out at different fermentation conditions. At 25°C, 35°C and 45°C, the biogas yield from fermentation of Ulva pertusa were 223.2mL/gVS, 256.2mL/gVS and 300.0mL/gVS,respectively, while the methane content in the biogas produced at 35°C was the highest. In addition, biogas yield reached to 482.5mL/gVS and 499.6mL/gVS by adding waste paper of 3.5g and 7.0g to the fermentation liquor, the corresponding methane content in the biogas were 56.0% and 51.2%, respectively. Comparatively, higher biogas yield, methane content and system stability could obtain from Ulva pertusa by adding 3.5g ~ 7.0g of waste paper and fermentation at 35°C.The fermentation process of Ulva pertusa for biogas production generally lasted for 19~25 days.

In this paper, crystallization kinetics behavior of a high heat-absorbing PET / TiN nanocomposite ,the effect of the crystallization behavior of adding nanoendothermic agent,and their crystallization rate and crystallization were studied by differential scanning calorimeter (DSC) ,researching the effect of crystallization behavior of PET with modified TiN and using Avrami equation to study non-isothermal crystallization kinetics. The results show that the kinetic rate constant Zc increasing with the increase of cooling rate, the crystallization half time t1 / 2 subsequently reduced, the crystal growth become fast; TiN is a good nucleating agent in PET, improve PET’s crystallization rate, adding TiN reduce the crystallization activation energy. This has important significance to guide nanocomposite processing.

This paper mainly describes a novel biodegradable material poly (butylene carbonate) (PBC) to blending toughing modification for polylactic acid (PLA), and prepared the PBC/PLA biodegradable film) of improved toughness. To research the effect of thermol performance and mechanical properties (tensile strength and breaking elongation rate) through Fourier transform infrared spectroscopy (FTIR), differential thermal scanning calorimetry analysis (DSC) and tensile testing to expound different ratio of PBC and additive plasticizer, (lubricant and chain extender) .

This paper details the preparation of one kind of PEG/MMT solid-solid phase change materials. With polyethylene glycol (PEG) as the phase change materials, montmorillonite (MMT) as skeletons, through the graft copolymerization method, prepare PEG/MMT solid-solid phase change energy storage materials. The structure, the phase transition behavior and thermal stability of PEG/MMT phase change materials were analyzed and studied by infrared spectroscopy (FTIR), thermogravimetry (TG) and differential scanning calorimetry (DSC), and studied the influence of different molecular weight PEG on the capability and structure of the material, polymer phase change energy storage behavior and crystallization behavior. Finally, The PEG/MMT solid-solid phase change material could improve enthalpy value and thermal stability.

A novel method is proposed to modify montmorillonite with coupling agents and Hexadecyl triphenyl phosphonium bromide surfactants made by our group (named P-surfactant in the following). The structure of organophilic montmorillonite (OMMT) was investigated by FT-IR, XRD and TG. The FT-IR shows the coupling agents were inserted between the layers of MMT and reacted with –OH of MMT. The results of X-ray diffraction shows that the coupling agents were all intercalated into the layers of MMT. The interlayer spacing of montmorillonite increases to 4.00 nm, the effect of modification is well. The results of TG showed the thermal stability was better.

Abstract.In this paper, the nonisothermal crystallization kinetics was investigated by differential scanning calorimetry for the poly(m-xylylene adipamide) (MXD6) which were prepared by polymerization in reactor. The Avrami theory modified by Jeziorny and Z.S. Mo equation were used to describe the nonisothermal crystallization kinetics. The analysis based on the Avrami theory modified by Jeziorny shows that the Avrami exponent n of MXD6 ranges from 2.3 to 3.3, Moreover, both Avrami exponent (n) were around 3.0, which probably suggests a thermal nucleation and a three-dimensional crystal growth. The good linearity of the plots indicates the successful application of Z.S. Mo method in this case.