DLP 3D printed ionic hydrogels are designed as sensitivity-improved electrodes in a skin-like sensor.

Solar steam generation is one of the most promising solar-energy-harvesting technologies to address the issue of water shortage. Despite intensive efforts to develop high-efficiency solar steam generation devices, challenges remain in terms of the relatively low solar thermal efficiency, complicated fabrications, high cost, and difficulty in scaling up. Herein, a double-network hydrogel with a porous structure (p-PEGDA-PANi) is demonstrated for the first time as a flexible, recyclable, and efficient photothermal platform for low-cost and scalable solar steam generation. As a novel photothermal platform, the p-PEGDA-PANi involves all necessary properties of efficient broadband solar absorption, exceptional hydrophilicity, low heat conductivity, and porous structure for high-efficiency solar steam generation. As a result, the hydrogel-based solar steam generator exhibits a maximum solar thermal efficiency of 91.5% with an evaporation rate of 1.40 kg m h under 1 sun illumination, which is comparable to state-of-the-art solar steam generation devices. Furthermore, the good durability and environmental stability of the p-PEGDA-PANi hydrogel enables a convenient recycling and reusing process toward real-life applications. The present research not only provides a novel photothermal platform for solar energy harvest but also opens a new avenue for the application of the hydrogel materials in solar steam generation.

The economic and safety issues caused by ice accretion have become more and more serious. Except for traditional ways of anti‐icing, such as spraying agents, mechanical/thermal removal, etc., more economic approaches are urgently required. This work demonstrates the conceptual feasibility of using a self‐lubricated photothermal coating for both anti‐icing and deicing function. The coating is generally water repellent and infiltrated with hydrocarbon or perfluorocarbon oils as the lubricant to endow a liquid interface for preventing ice accumulation and minimizing the adhesion of ice on surfaces once it is formed. Fe3O4 nanoparticles are added to the film to afford high efficiency photothermal effect under near‐infrared irradiation for rapidly melting the accumulated ice. The conceptual strategy can be easily implemented as a facile method to fabricate analogous sprayed coatings. It represents a major advance to tackle the challenging icing issue that is normally seen as a disaster in everyday life.

Artificial "ionic skin" is of great interest for mimicking the functionality of human skin, such as subtle pressure sensing. However, the development of ionic skin is hindered by the strict requirements of device integration and the need for devices with satisfactory performance. Here, a dual-material printing strategy for ionic skin fabrication to eliminate signal drift and performance degradation during long-term use is proposed, while endowing the ionic skins with high sensitivity by 3D printing of ionic hydrogel electrodes with microstructures. The ionic skins are fabricated by alternative digital light processing 3D printing of two photocurable precursors: hydrogel and water-dilutable polyurethane acrylate (WPUA), in which the ionically conductive hydrogel layers serve as soft, transparent electrodes and the electrically insulated WPUA as flexible, transparent dielectric layers. This novel dualmaterial printing strategy enables strong chemical bonding between the hydrogel and the WPUA, endowing the device with designed characteristics. The resulting device has high sensitivity, minimal hysteresis, a response time in the millisecond range, and excellent repetition durability for pressure sensing. The results demonstrate the potential of the dual-material 3D printing strategy as a pathway to realize highly stable and high-performance ionic skin fabrication to monitor human physiological signals and humanmachine interactions.

Solar desalination of seawater is an attractive and environmentally friendly method to solve the long-standing water crisis. However, its efficiency is highly reliant on solar intensity. Additionally, increasing contamination in water makes it difficult to generate clean water through the solo desalination process. To address this, we propose a polydopamine (PDA)-functionalized hybrid material with dual-purpose solar evaporation and contaminant adsorption for highly efficient clean water production in all-weather conditions. The hybrid material is fabricated by polymerization of dopamine onto a commercial sponge in a facile, low-cost, and scalable manner. With excellent light absorption and chelation capabilities, the PDA film coated on sponge acts as both a photothermal material and adsorbent that allow us to achieve clean water production with solar desalination when sunshine and with contaminant adsorption when cloudy or at night. Meanwhile, the solar evaporation and contaminant adsorption of the PDA-sponge are synergized with one another, resulting in the PDA-sponge that is a desirable material with the capability of continuous clean water production in all-weather conditions. The PDA-sponge is also highly recyclable with a high retention rate of evaporation and adsorption efficiency even after 10 cycles. The promising PDA-based hybrid is believed to inspire new strategies for superior water treatment materials.

3D printable thermoreversible polyurethanes (PDAPUs) are synthesized, which facilitate the manufacturing of smart devices with 3D structures. The cross-linking of aniline trimer in PDAPUs plays a critical role in realizing light controllable precise selfhealing and targeted shape memory.

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