AB STRACT: A suspended growth photobioreactor was utilized to treat pharmaceutical wastewater by a wild strain purple non-sulfur photosynthetic bacterium isolated from the soil. The strain was named Z08 and identified as Rhodobacter-sphaeroides by 16SrDN. The photobioreactor was illuminated externally with two (40 W) fluorescent compact light sources on both sides. Its operation pH and temperature were between 6.8 -7.0 and 20 -30 ºC, respectively. Optimum growth of the isolate was obtained after enrichment of the pharmaceutical wastewater with 0.5 % ammonium sulfate and 0.1 % yeast extract under microaerobic optimum light (6000 lx) condition at 5d retention. Using these optimum conditions, the maximum dry cell weight and chemical oxygen demand percentage removal were 880 mg/L and 80 %. Chemical analysis of the culture after treatment of the enriched and non-enriched wastewater showed the crude protein content of the biomass to be 54.6 % and 38.0 %, respectively. This study proved that photosynthetic bacteria could transform complex wastewater that contains recalcitrant organic compounds with a resultant recovery of useful products.
Layer-structured black phosphorus (BP) demonstrating high specific capacity has been viewed as a very promising anode material for future high-energy-density Li-ion batteries (LIBs). However, its practical application is hindered by large volume change of BP and poor mechanical stability of BP anodes by traditional slurry casting technology. Here, a free-standing flexible anode composed of BP nanosheets and nanocellulose (NC) nanowires is fabricated via a facile vacuum-assisted filtration approach. The constructed free-standing BP@NC composite anode offers three-dimensional (3D) mixed-conducting network for Li+/e– transports. The substrate of NC film has a certain flexibility up to 10.2% elongation that can restrain the volume change of BP and electrode during operation. In addition, molecular dynamic (MD) simulation and density function theory (DFT) show the greatly enhanced Li+ diffusion in BP@NC composite where the Li ions receive less repulsive force at the interface of BP interlayer and nanocellulose. Benefiting from above multifunction of nanocellulose, the BP@NC composite exhibits high capacities of 1020.1 mAh g–1 at 0.1 A g–1 after 230 cycles and 994.4 mAh g–1 at 0.2 A g–1 after 400 cycles, corresponding to high capacity retentions of 87.1% and 84.9%, respectively. Our results provide a low-cost and effective strategy to develop advanced electrodes for next-generation rechargeable batteries.
Layered metal oxide cathodes suffer from a low specific capacity (below 200 mAh g −1 ), while long-term capacity retention is limited by electrolyte decomposition at high voltage (>4.5 V), decohesion, and fracture in primary grains upon cycling. Here, LiNi 0.5 Co 0.2 Mn 0.3 O 2 (NCM523) at 4.8 V, employing p-toluenesulfonyl isocyanate (PTSI) as an electrolyte additive, has been investigated, which shows much improved cycling capabilities and rate performances for long-term cycling when a cell voltage of 4.8 V is applied. On the basis of the electrochemical analysis results and the first-principles calculation, the product CH 3 C 6 H 4 NCO from PTSI can be polymerized to produce a polymer (CH 3 C 6 H 4 NCO) 2 to generate a stable solid electrolyte interphase film on the NCM523 cathode, which inhibits the decomposition of the electrolyte upon cycling at 4.8 V and offers a long-term cycling performance over 680 cycles. This work emphasizes that in situ surface protection induced by electrolyte additives can drive stable cycling of layered metal oxide cathodes at 4.8 V in advanced Li-ion batteries.
Acute gouty arthritis is the inflammation of joint tissues in the acute form due to the deposition of monosodium urate (MSU) crystals. Regulatory T cells (Tregs) and Th17 cells play an important role in the development and progression of inflammatory diseases. However, the expression and role of Tregs and Th17 cells are not clear in this disease. Here, we investigated the changes of Tregs, Th17 cells, and Treg/Th17 ratio in spleen, as well as the inflammatory cytokines in blood and joint tissue pathology in acute gouty arthritis rat induced by MSU. We found that both the percentages of Tregs and Th17 cells in spleen increased at an early stage (6 h). Tregs decreased at 12 and 24 h, and rise again at 48 and 72 h. However, Th17 cells reached its peak at 24 h, and then decreased after 48 h. Treg/Th17 ratio showed an initial decrease and then increase, and further reached its minimum value at 24 h. But the ratios of Treg/Th17at all times were lower than that of normal control. The level of serum cytokines (IL-1β, IL-6, IL-17, TNF-α, and IL-10) showed an opposite trend to Treg/Th17 ratio, except the level of TGF-β was similar to Tregs. In summary, Tregs and Th17 cells in spleen changed over time during the development of acute gouty arthritis. Decrease of Treg/Th17 ratio was consistent with inflammation development in the joints, suggesting that Treg/Th17 imbalance may involve in pathogenesis of acute gouty arthritis.
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