A mid-infrared (MIR) supercontinuum (SC) has been demonstrated in a low-loss telluride glass fiber. The doublecladding fiber, fabricated using a novel extrusion method, exhibits excellent transmission at 8-14 μm: < 10 dB/m in the range of 8-13.5 μm and 6 dB/m at 11 μm. Launched intense ultrashort pulsed with a central wavelength of 7 μm, the step-index fiber generates a MIR SC spanning from ß2.0 μm to 16 μm, for a 40-dB spectral flatness. This is a fresh experimental demonstration to reveal that telluride glass fiber can emit across the all MIR molecular fingerprint region, which is of key importance for applications such as diagnostics, gas sensing, and greenhouse CO 2 detection.
Three groups of Ge–Sb–Se
glasses with compositions
Ge
x
Sb10Se90–x
, Ge
x
Sb15Se85–x
, and Ge
x
Sb20Se80–x
have
been systematically studied with the aim of understanding the role
of chemical composition and mean coordination number (MCN) in determining
their structural and physical properties. For each group of glasses,
it was found that the optical bandgap increases and the refractive
index decreases with increasing Ge concentration up to a transition
point which corresponds to glasses that have chemically stoichiometric
compositions. Raman spectra were measured and decomposed into different
structural units. While the relative number of the heteropolar bonds
changes in a reasonable manner with chemical composition, the evolution
of the optical bandgap and refractive index correlated closely with
the number of the homopolar bonds, suggesting that the band-tails
formed by homopolar bonds could reduce the optical bandgap. On the
other hand, the transitions at the chemically stoichiometric compositions
could be attributed to “demixing” of networks above
the chemical thresholds. These transition thresholds in the three
groups of glasses demonstrated that the chemical composition has significant
effects on the physical properties in the Ge–Sb–Se system.
Crystallization
kinetics of phase change materials (PCMs) at high
temperatures is of key importance for the extreme speed of data writing
and erasing. In this work, the crystallization behavior of one of
the typical PCMs, GeTe, has been studied using ultrafast differential
scanning calorimetry (DSC) at high heating rates up to 4 × 104 K s–1. A strong non-Arrhenius temperature-dependent
viscosity has been observed. We considered two viscosity models for
estimating the crystal growth kinetics coefficient (U
kin). The results showed that the MYEGA model was more
suitable to describe the temperature-dependent viscosity and the crystal
growth kinetics for supercooled liquid GeTe. The glass transition
temperature (T
g) and fragility m were estimated to be 432.1 K and 130.7, respectively.
The temperature-dependent crystal growth rates, which were extrapolated
by the MYEGA model, were in line with the experimental results that
were measured by in situ transmission electron microscopy at a given
temperature. The crystal growth rate reached a maximum of 3.5 m s–1 at 790 K. These results based on ultrafast DSC with
the MYEGA model offer a revelation for crystallization kinetics of
supercooled liquid GeTe.
A miniature polarimetric interferometer with the twist of a highly-birefringent microfiber is demonstrated. Good transmission spectral characteristics, which are co-governed by the birefringence and the twist degree of the microfiber, are investigated. The structure exhibits extremely-high sensitivity of around 24,373 nm per refractive-index unit and excellent temperature stability of better than 0.005 nm/°C. Featured with compactness, reconfigurability, stability, robustness, and compatibility with other fiberized components, our device has potential in tunable filtering, sensing, multi-wavelength lasing, and etc.
Surface plasmon resonance (SPR) of noble metal nanoparticles (NPs) fostered a new area of nanophotonics, especially in the selective photon absorption and scattering. The precipitation of Ag NPs in glass would enhance the emission efficiency. Here, we studied the effects of annealing temperature (resulted in the increased Ag NPs’ concentration) or AgCl concentration on the luminescence properties of Er3+/Yb3+ codoped bismuth-germanate glasses which were synthesized by a single-step melting–quenching technique. The SPR peak of Ag NPs appears around 600 nm, and the size of precipitated Ag NPs (spherical, hexagonal) ranges from 5 to 15 nm. With the precipitation of the Ag NPs, more intense green (527 nm, 548 nm) and red (661 nm) upconversion (UC) emission bands are observed up to 7.7, 10.1, and 6.5 folds in the glass containing 1 wt % AgCl annealed at 480 °C for 24 h, respectively. The Ag NPs embedded glasses showed significantly local field change that allowed for more bright UC emission by SPR.
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