MXenes represent a large family of functionalized two-dimensional (2D) transition-metal carbides and carbonitrides. However, most of the understanding on their unique structures and applications stops at the theoretical suggestion and lack of experimental support. Herein, the surface structure and intercalation chemistry of Ti3C2X are clarified at the atomic scale by aberration-corrected scanning transmission electron microscope (STEM) and density functional theory (DFT) calculations. The STEM studies show that the functional groups (e.g., OH(-), F(-), O(-)) and the intercalated sodium (Na) ions prefer to stay on the top sites of the centro-Ti atoms and the C atoms of the Ti3C2 monolayer, respectively. Double Na-atomic layers are found within the Ti3C2X interlayer upon extensive Na intercalation via two-phase transition and solid-solution reactions. In addition, aluminum (Al)-ion intercalation leads to horizontal sliding of the Ti3C2X monolayer. On the basis of these observations, the previous monolayer surface model of Ti3C2X is modified. DFT calculations using the new modeling help to understand more about their physical and chemical properties. These findings enrich the understanding of the MXenes and shed light on future material design and applications. Moreover, the Ti3C2X exhibits prominent rate performance and long-term cycling stability as an anode material for Na-ion batteries.
Two-dimensional (2D) transition-metal dichalcogenides hold enormous potential for applications in electronic and optoelectronic devices. Their distinctive electronic and chemical properties are closely related to the structure and intercalation chemistry. Herein, the controversial phase transition from semiconductive 2H to metallic 1T phase and occupancy of the intercalated sodium (Na) upon electrochemical Na intercalation into MoS2 are clarified at the atomic scale by aberration-corrected scanning transmission electron microscope. In addition, a series of other complicated phase transitions along with lattice distortion, structural modulation, and even irreversible structural decomposition are recognized in MoS2 depending on the content of Na ion intercalation. It is shown that x = 1.5 in Na(x)MoS2 is a critical point for the reversibility of the structural evolution. Our findings enrich the understanding of the phase transitions and intercalation chemistry of the MoS2 and shed light on future material design and applications.
Biological synapses store and process information simultaneously by tuning the connection between two neighboring neurons. Such functionality inspires the task of hardware implementation of neuromorphic computing systems. Ionic/electronic hybrid three-terminal memristive devices, in which the channel conductance can be modulated according to the history of applied voltage and current, provide a more promising way of emulating synapses by a substantial reduction in complexity and energy consumption. 2D van der Waals materials with single or few layers of crystal unit cells have been a widespread innovation in three-terminal electronic devices. However, less attention has been paid to 2D transition-metal oxides, which have good stability and technique compatibility. Here, nanoscale three-terminal memristive transistors based on quasi-2D α-phase molybdenum oxide (α-MoO ) to emulate biological synapses are presented. The essential synaptic behaviors, such as excitatory postsynaptic current, depression and potentiation of synaptic weight, and paired-pulse facilitation, as well as the transition of short-term plasticity to long-term potentiation, are demonstrated in the three-terminal devices. These results provide an insight into the potential application of 2D transition-metal oxides for synaptic devices with high scaling ability, low energy consumption, and high processing efficiency.
capacity of the modified oxide reaches 320 mAh g -1 in the initial cycle, 94.5% of which remains after 100 cycles. More importantly, the average discharge potential drops only by 136 mV in this process. Our findings illustrate the importance of inactivating the surface oxygen in suppressing the cation mixing in the bulk, providing an effective strategy for designing high-performance Li-rich cathode materials.
Resistive switching processes in HfO are studied by electron holography and in situ energy-filtered imaging. The results show that oxygen vacancies are gradually generated in the oxide layer under ramped electrical bias, and finally form several conductive channels connecting the two electrodes. It also shows that the switching process occurs at the top interface of the hafnia layer.
Thermomagnetic irreversibility and magnetic short range ordering in Mn 2.5 Co 0.5 O 4 tetragonal spinel thin films J. Appl. Phys. 107, 09E152 (2010); 10.1063/1.3364051 Room-temperature ferrimagnetic semiconductor 0.6 Fe Ti O 3 • 0.4 Fe 2 O 3 solid solution thin films
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