From well-controlled long creep tests, we show that the residual apparent yield stress observed with soft-jammed systems along smooth surfaces is an artifact due to edge effects. By removing these effects, we can determine the stress solely associated with steady-state wall slip below the material yield stress. This stress is found to vary linearly with the slip velocity for a wide range of materials whatever the structure, the interaction types between the elements and with the wall, and the concentration. Thus, wall slip results from the laminar flow of some given free liquid volume remaining between the (rough) jammed structure formed by the elements and the smooth wall. This phenomenon may be described by the simple shear flow in a Newtonian liquid layer of uniform thickness. For various systems, this equivalent thickness varies in a narrow range (35±15 nm).
We carry out a series of experiments with the aim of completing our knowledge of wall slip characteristics, through a deductive approach based on macroscopic behavior observations. More precisely, we use model materials (direct and inverse emulsions) and determine the variations of wall slip properties depending on the material parameters (droplet size, concentration) and boundary conditions of the flow (free surface or flow between two solid surfaces, normal force, flow beyond yielding, and coated or rough surface). The wall slip characteristics are determined from long creep tests at different levels and from internal measurements of the velocity profile in the capillary or the Couette flow as determined by magnetic resonance imaging. First, we show that the slip yield stress is due either to edge effects in relation with evaporation then pinning around the line of contact or to a kind of adhesion of the suspended elements to the wall. This adhesion effect varies with the characteristics of the solid surface (interaction with elements, roughness), and wall slip (below the yield stress) disappears when the adhesion or adherence leads to a wall slip yield stress expected to be larger than the material yield stress. Then, we show that, below the yield stress, the slip velocity vs shear stress (from which the slip yield stress has been removed) relationship is linear. The corresponding value for the apparent slip layer made of interstitial liquid appears to be independent of the concentration and to vary only slightly with the droplet size. Moreover, it is independent of the normal force (below the critical value inducing elongation) and other experimental conditions, e.g., it is the same for free surface flows. Although the origin of this phenomenon remains to be found, the following scheme appears to be consistent with all observations: the droplets are attracted at a very short distance from the wall, forming regions of small area in which the liquid layer thickness is very small, the shear stress being dominated by the shear in these regions. Finally, this apparent layer thickness increases at the approach of the yield stress and beyond, or if a slightly rough surface is used, leading to a faster (quadratic?) variation of the slip velocity as a function of the stress.
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