It is an enormous challenge to construct high-energy-density materials meeting simultaneously requirements of high energy and excellent stability. In this work, the reaction of a Ag(I) ion with a nitrogen-rich ligand, 1H-tetrazole-5-acetic acid (H 2 tza), leads to a novel Ag7-cluster metal−organic framework, [Ag 7 (tza) 3 (Htza) 2 (H 2 tza)(H 2 O)] (1), with remarkable highenergy content, stability, and insensitivity. Dramatically, the heatingdehydrated process of 1 produces a new stable energetic material, [Ag 7 (tza) 3 (Htza) 2 (H 2 tza)] (1a), which features superior energy and undiminished safety performance compared to those of 1.
Host–Guest
interaction is crucial to the sensitivity of
heterogeneous sensors. Here, a series of isomorphic three-dimensional
lanthanide metal–organic frameworks (Ln-MOFs), [Ln(TCBA)(H2O)2]2·DMF [H
3
TCBA = tris(3′-carboxybiphenyl)amine;
Ln = Tb (1), Eu (2), and Gd (3); DMF = dimethylformamide] was synthesized and characterized, in
which the propeller-like TCBA
3–
ligands adopt special torsional link between Tb(III) ions
to form one-dimensional triangular channels. Optical experiments show
that 1 exhibits bright green luminescence with an overall
quantum yield of 26%, a 5D4 lifetime of 478
μs, and can act as an excellent heterogeneous fluorescent sensor
to detect 2,4,6-trinitrophenol (TNP) explosive with an
extremely low detection limit of 1.64 ppb. Because the confined channels
within 1 exhibit matched dimensions toward TNP and feature multiple guest-response sites including rich π-conjugated
groups, electron-donating N centers, and open metal nodes, strong
host–guest interactions between 1 and TNP are captured and accurately determined by online microcalorimetry,
which provides a distinctive thermodynamic perspective to understand
the heterogeneous sensing behaviors. Additionally, the finely modulated
heterometallic isomorphism [Tb0.816Eu0.184(TCBA)(H2O)2]2·DMF
emits bright white light when excited at 380 nm and could potentially
be used as single-phase white light-emitting diode phosphors materials.
Uncontrolled
flow through different permeability zones in oil reservoirs
remains a huge challenge during water flooding, which can significantly
limit microbial-enhanced oil recovery (MEOR)) efficiency. The aim
of the present work was to use polymer-based plugging to assist MEOR
through laboratory simulation and field tests. An indigenous strain
HB3 was evaluated under field-relevant conditions. A polymeric HPAM/Cr(III)
plugging system was optimized which was also compatible with the microorganism.
Laboratory-based simulation demonstrated the selective plugging with
HPAM/Cr(III) resulting in enhanced oil recovery more significantly
in the low-permeability core, increasing from 12.8% to 47.5%, compared
to that in the high-permeability one, from 47.1% to 63.2%. A subsequent
microbial injection enhanced the oil recovery further, also with more
effective enhancement in the low-permeability core, increasing from
49.5% to 70.0% while from 67.5% to 78.0% in the high-permeability
one. The field tests involving two water injection and nine oil production
wells confirmed the improvement of deep profile control by polymer-based
plugging, resulting in a more uniform distribution of water absorption.
With subsequent microbial injection, oil recovery was significantly
enhanced, achieving an ultimate recovery of 57.6% and a cumulative
oil increment of 3486 t in nine wells over the 7 month field tests.
It was demonstrated that the application of polymer-based plugging
significantly improved MEOR efficiency, providing a new route for
EOR, especially for heterogeneous reservoirs.
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