The article presents the results of research on the influence of two fuel additives that selectively affect the combustion process in a diesel engine cylinder. The addition of NitrON® reduces the concentration of nitrogen oxides (NOx), due to a reduction in the kinetic combustion rate, at the cost of a slight increase in the concentration of particulate matter (PM) in the engine exhaust gas. The Reduxco® additive reduces PM emissions by increasing the diffusion combustion rate, while slightly increasing the NOx concentration in the engine exhaust gas. Research conducted by the authors confirmed that the simultaneous use of both of these additives in the fuel not only reduced both NOx and PM emissions in the exhaust gas but additionally the reduction of NOx and PM emissions was greater than the sum of the effects of these additives—the synergy effect. Findings indicated that the waveforms of the heat release rate (dQ/dα) responsible for the emission of NOx and PM in the exhaust gas differed for the four tested fuels in relation to the maximum value (selectively and independently in the kinetic and diffusion stage), and they were also phase shifted. Due to this, the heat release process Q(α) was characterized by a lower amount of heat released in the kinetic phase compared to fuel with NitrON® only and a greater amount of heat released in the diffusion phase compared to fuel with Reduxco® alone, which explained the lowest NOx and PM emissions in the exhaust gas at that time. For example for the NOx concentration in the engine exhaust: the Nitrocet® fuel additive (in the used amount of 1500 ppm) reduces the NOx concentration in the exhaust gas by 18% compared to the base fuel. The addition of a Reduxco® catalyst to the fuel (1500 ppm) unfortunately increases the NOx concentration by up to 20%. On the other hand, the combustion of the complete tested fuel, containing both additives simultaneously, is characterized, thanks to the synergy effect, by the lowest NOx concentration (reduction by 22% in relation to the base). For example for PM emissions: the Nitrocet® fuel additive does not significantly affect the PM emissions in the engine exhaust (up to a few per cent compared to the base fuel). The addition of a Reduxco® catalyst to the fuel greatly reduces PM emissions in the engine exhaust, up to 35% compared to the base fuel. On the other hand, the combustion of the complete tested fuel containing both additives simultaneously is characterized by the synergy effect with the lowest PM emission (reduction of 39% compared to the base fuel).
Wpływ dodatku zwiększającego liczbę cetanową na właściwości zapłonowe i proces spalania oleju napędowego w silniku o zapłonie samoczynnym W artykule przedstawiono proces tworzenia mieszanki paliwowo-powietrznej w silniku z zapłonem samoczynnym oraz czynniki mające wpływ na właściwości zapłonowe oleju napędowego, w tym na opóźnienie fizyczne i chemiczne zapło-nu. Zaprezentowano również mechanizm przebiegu reakcji chemicznych obniżających opóźnienie zapłonu chemicznego przy użyciu alkiloazotanu jako dodatku cetanowego.Słowa kluczowe: mieszanka paliwowo-powietrzna, opóźnienie fizyczne i chemiczne zapłonu, reakcje przedpłomieniowe, azotan alkilu.
The effect of the cetane number improver on the ignition properties and combustion process of diesel fuel in a compression ignition engineThis article presents the process of establishing the air/fuel mixture in a compression-ignition engine, and the factors that affect the ignition properties of the diesel fuel, including the physical and chemical delay of the ignition. The mechanism of the chemical reactions that reduce the chemical delay using alkyl nitrate as a cetane improver was also presented.
This publication is the next part of the article “The influence of cetane-detergent additives in diesel fuel increased to 10% of RME content on energy parameters and exhaust gas composition of a diesel engine”. The cause-effect analysis of the phenomena related to the impact of 3 additive packages used in diesel oil with RME content increased to 10% (compare to standard diesel fuel with 7% of RME) was described. The basis for the analysis of the impact of the tested fuels on energy parameters and composition of exhaust gases were the parameters of indicator diagrams and heat release parameters. It was found that the first set of additives affects the delay of auto-ignition of fuel and kinetic fuel combustion speed only at low engine loads. In this range of engine operation the NOx concentration in the exhaust gas is low and besides there is a large of EGR.The second additive package was operated at high engine loads but its impact on the lower self-ignition delay was quantitatively small. Therefore, in the third packet of additives, the amount of additives used in the second packet was doubled. Then a satisfactory shortening of the self-ignition delay and reduction of the max rate of kinematic heat release was achieved as a reason of a reduction of NOx concentration in the exhaust up to 8% (compared to the reference fuel).
The paper provides information on the research and development works related to the design of diesel engines including the improvement of fuel combustion processes and reduction of its consumption, and limitation of exhaust emissions.
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