Background:The water pollution of Tigris River is considered the main increasing problem in Mosul city, Iraq. The divalent lead ions are direct or indirect toxic heavy metals ions contaminant confirmed as non-biodegradables and have a long half-life due to corrosions and sedimentation of these metal ions in storm sewer trunk mains, the critical issue is eliminating these heavy metal ions by treating wastewater via commercial activated carbon (CAC), which is the most effective used adsorbent in the adsorption process. Aim: This study aimed to eliminate divalent lead ions by treating wastewater using commercial activated carbon (CAC). Methodology: The surface of commercial activated carbon (CAC) was modified by using concentrated nitric acid. For this purpose, nitric acid in different concentrations (2, 4, 6, 8, and 10 M) and different temperatures (25, 50, 75, and 100( °C were used.Results and Discussion: The best results were observed at 50 °C in which it was used as a standard temperature. A 10 M nitric acid concentration was noticed as the best one. It could be observed that the high pore volume observed in modified activated carbon samples (estimated as the highest adsorption capacity towards iodine, using iodine number determination method) was (707.2 mg/g). This result was supported by methylene blue (190 mg/g). The modified activated carbon (MAC) at the chosen acid concentration was a useful filter to remove the methylene blue organic dye. The modified activated carbon (MAC) was used to adsorbed Pb 2+ ions from the Mosul Tigris river wastewaters, the percentage of mean changed activated carbon (MAC) surface adsorption removal efficiency of divalent lead ions were increased by 219% compared with the commercial activated carbon (CAC) Conclusions: : Using the methods for iodine number, ash content, methylene blue and density determinations, it was proven that the excellent sorption properties, strong microporous structure, large pore volume, surface of the acidic character, and porosity are the most critical chemical characterization parameters
Modification of asphaltic materials with polymeric materials and other additives is one of the most important processes or modifications that take place on asphalt materials. The purpose of these modified that take place is to obtain asphaltic materials with a good specifications in the field of paving, flattening or as a mastic. This study included the treatment of asphaltic materials with modified materials represented by polyvinyl chloride and spent lubricating oils. The asphalt was treated with these additives in different percentages and in the presence of sulfur with anhydrous ferric chloride as acatalyst at a temperature of 150 ° C. An air blowing process was used on both paths. The rheological properties of the original asphalt and the modified and original samples were measured (penetration, softining point and ductility In addition, penetration index was calculated) for all samples After that, the samples were left for the aging factors for a period of 12 months. The rheological properties were measured again.
Obtaining asphalt that suits the nature of the countries it is used in, is of great importance. Asphalt constitutes an important component in the paving of roads, mastic and flattening substance. This study was included the modification of the asphaltic material by the use of a mixture of polycarbonate and polymethyl methacrylate after crushed to obtain low molecular weight. The study included two paths: In the first asphaltic materials was treated with different percentages of a mixture in the presence of anhydrous aluminium chloride (0.06%of weight) as a catalyst for this reaction. The mixture was heated at 150° for 30 minutes. In the second path, the process of mixing was performed with the existence of a 360 watt microwave radiation for 15 minutes. The process of mixing was repeated in the presence of sulphur (1% of weight) instead of anhydrous aluminium chloride and under the same conditions. Properties of the original and modified asphalts were determined, and this included the measurement of ductility, penetration, softening point, penetration index and calculating the percentage of separated asphaltenes. Additionally, Marshal test, chemical Immersion test and aging were measured for some of the samples. Good samples that can suit Iraq's climate were obtained from this study.
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