NaInS2 und das bislang unbekannte leuchtend rote NaInSe2 sind wie NaInO2 dem α‐NaFeO2 isotyp. Die Abmessungen der hexagonalen Elementarzelle (Z = 3) sind a = 3,80 Å; c = 19,89 Å (NaInS2) bzw. a = 3,97 Å; c = 20,89 Å (NaInSe2). Das Auftreten des α‐NaFeO2‐Typs bei beiden Verbindungen wird kurz diskutiert.
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