1961
DOI: 10.1002/zaac.19613090105
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Zur Kenntnis von NalnS2 und NalnSe2

Abstract: NaInS2 und das bislang unbekannte leuchtend rote NaInSe2 sind wie NaInO2 dem α‐NaFeO2 isotyp. Die Abmessungen der hexagonalen Elementarzelle (Z = 3) sind a = 3,80 Å; c = 19,89 Å (NaInS2) bzw. a = 3,97 Å; c = 20,89 Å (NaInSe2). Das Auftreten des α‐NaFeO2‐Typs bei beiden Verbindungen wird kurz diskutiert.

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Cited by 47 publications
(16 citation statements)
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“…35 The distances of In-Se range from 2.558(2) to 2.571(3) Å, a little shorter than those in NaInSe 2 (2.758 Å). 35 The Ge-Se bond lengths of 2 Se1, Se2, Se3, Se4, Se5 and Se6, respectively) are also close to the expected value.…”
Section: Page 7 Of 30 Dalton Transactionsmentioning
confidence: 97%
“…35 The distances of In-Se range from 2.558(2) to 2.571(3) Å, a little shorter than those in NaInSe 2 (2.758 Å). 35 The Ge-Se bond lengths of 2 Se1, Se2, Se3, Se4, Se5 and Se6, respectively) are also close to the expected value.…”
Section: Page 7 Of 30 Dalton Transactionsmentioning
confidence: 97%
“…The coordination number of the In center in chalcogenides also varies. It is often four (LiInTe 2 [3], NaInTe 2 , KInTe 2 [4], and KInS 2 , [5]), but six is also common (NaInS 2 and NaInSe 2 [6]). The composition and coordination versatility play important roles in the structural diversity of the A/In/Q family.…”
Section: Introductionmentioning
confidence: 99%
“…NaInTe 2 is isostructural with TlSe, crystallizing in space group I4/mcm of the tetragonal system [4]. NaInS 2 exhibits the a-NaFeO 2 structure (space group R3m of the trigonal system) [6], which is an ordered structure of a rock salt derivative. These two structural types are usually high-pressure forms in the AInQ 2 system.…”
Section: Introductionmentioning
confidence: 99%
“…Die bisher bekannten Thioindate der Alkalimetalle besitzen durchweg die Formel MInS2 (M = Li, Na, K, Rb, Cs) und sind sowohl im Rahmen von struktursystematischen Untersuchungen [1,2] als auch im Zusammenhang mit Hochdruckumwandlungen [3] mehrfach untersucht worden.…”
Section: Introductionunclassified