This review addresses the formation, fabrication methods, properties and applications of wrinkled patterns in 2D materials.

High stretchability and sensitivity of strain sensors are two properties that are very difficult to combine together into one material, due to the intrinsic dilemma of the opposite requirements of robustness of the conductive network. Therefore, the improvement of one property is always achieved at the expense of decreasing the other property, and preventing its practical application. Inspired by the micro-structure of the copolymer, which consists of stretchable amorphous and strong crystal domains, we developed a highly stretchable and sensitive strain sensor, based on innovative gradient carbon nanotubes (CNTs). By integrating randomly oriented and well aligned CNTs, acting as sensitive and stretchable conductive elements, respectively, into a continuous changing structure, our strain sensors successfully combine both a high sensitivity (gauge factor (GF) = 13.5) and ultra-stretchability (>550%). With a fast response speed (<33 ms) and recovery speed (<60 ms), lossless detection of a 8 Hz mechanical signal has been easily realized. In addition, the gradient CNTs strain sensors also showed great durability in a dynamic test of 12 000 cycles, as well as extraordinary linearity and ultra-low working voltage (10 mV). These outstanding features mean our sensors have enormous potential for applications in health monitoring, sports performance monitoring and soft robotics.

Nanofiller/polymer nanocomposites are promising dielectrics for energy harvesting to be applied in wearable and flexible electronics. The structural design of the nanofillers plays a vital role to improve the energy storage performance of the related nanocomposites. Here, we fabricate a flexible device based on nonsolid titanium oxide (TiO x ) nanoparticles/poly(vinylidene fluoride) (PVDF) to achieve enhanced energy storage performance at low loading. The room-temperature oxidation method is used to oxidize two-dimensional MXene (Ti 3 C 2 T x ) flakes to form partially hollow TiO x nanoparticles. Taking advantage of this structure, the flexible TiO x nanoparticles/ PVDF nanocomposite with an ultralow loading content of 1 wt % nanofillers shows high energy storage performance, including a dielectric constant of ≈22 at 1 kHz, a breakdown strength of ≈480 MV m −1 , and an energy storage density of 7.43 J cm −3 . The finite element simulation further reveals that the optimization of the energy storage performance is ascribed to the lower electric potential among the partially hollow TiO x nanoparticles, which enhances the breakdown strength of the nanocomposites. This work opens a new avenue to structurally design and fabricate low-loading polymer-based nanocomposites for energy storage applications in next-generation flexible electronics.

Ceramic-polymer nanocomposites with high energy storage density can achieve excellent energy storage performance and have a wide range of application prospects. Currently, it has been shown that the coupling effects have a great impact on improving the performance of dielectric composites, but increasing the breakdown strength of polymer nanocomposite is still a tremendous challenge to the achievement of high energy density under high voltages. The aim of this paper is to further investigate this problem and obtain AgNbO 3 /PVDF flexible composites by introducing a small amount of AgNbO 3 ultrafine powder prepared by hydrothermal method into poly(vinylidene fluoride) (PVDF). The interfacial coupling effect within this nanocomposite with the coupling effects of nonlinear dielectric materials improves its energy storage capacity and electrical strength resistance. The energy density of the 2 wt% AgNbO 3 /PVDF composite film was raised to 16.5 J/cm 3 at the electric breakdown strength of 391.7 MV/m, and its energy storage capacity is two to three times that of AgNbO 3 lead-free antiferroelectric ceramics. Finite element simulations showed the further enhancement of breakdown strength was ascribed to the local electric field and to the AgNbO 3 ultrafine powder which blocked the breakdown path in the nanocomposites and coupling effects occurred with PVDF. Hence, the AgNbO 3 ultrafine powder has a positive effect on improving the energy storage performance of flexible composites. The effects of nonlinear dielectric material coupling effects and interfacial coupling effects on the dielectric properties of composite dielectric materials are further investigated, which are important for the development of flexible high energy storage capacitors.