Development of sorbent materials with high selectivity and sorption capacity, easy collection and recyclability is demanding for spilled oil recovery. Although many sorption materials have been proposed, a systematic study on how they can be reused and possible performance degradation during regeneration remains absent. Here we report magnetic carbon nanotube sponges (Me-CNT sponge), which are porous structures consisting of interconnected CNTs with rich Fe encapsulation. The Me-CNT sponges show high mass sorption capacity for diesel oil reached 56 g/g, corresponding to a volume sorption capacity of 99%. The sponges are mechanically strong and oil can be squeezed out by compression. They can be recycled using through reclamation by magnetic force and desorption by simple heat treatment. The Me-CNT sponges maintain original structure, high capacity, and selectivity after 1000 sorption and reclamation cycles. Our results suggest that practical application of CNT macrostructures in the field of spilled oil recovery is feasible.
Supramolecular self-assembly offers a powerful strategy to produce high-performance, stimuli-responsive nanomaterials. However, lack of molecular understanding of stimulated responses frequently hampers our ability to rationally design nanomaterials with sharp responses. Here we elucidated the molecular pathway of pH-triggered supramolecular self-assembly of a series of ultra-pH sensitive (UPS) block copolymers. Hydrophobic micellization drove divergent proton distribution in either highly protonated unimer or neutral micelle states along the majority of the titration coordinate unlike conventional small molecular or polymeric bases. This all-or-nothing two-state solution is a hallmark of positive cooperativity. Integrated modelling and experimental validation yielded a Hill coefficient of 51 in pH cooperativity for a representative UPS block copolymer, by far the largest reported in the literature. These data suggest hydrophobic micellization and resulting positive cooperativity offer a versatile strategy to convert responsive nanomaterials into binary on/off switchable systems for chemical and biological sensing, as demonstrated in an additional anion sensing model.
Because of profound genetic and histological differences in cancerous tissue, it is challenging to detect a broad range of malignant tumours at high resolution. Here, we report the design and performance of a fluorescent nanoprobe with transistor-like responses (transition pH = 6.9) for the detection of the deregulated pH that drives many of the invasive properties of cancer. The nanoprobe amplifies fluorescence signal in the tumour over that in the surrounding normal tissues, resulting in a discretized, binary output signal with spatial resolution smaller than 1 mm. The nanoprobe allowed us to image a broad range of tumours in mouse models using a variety of clinical cameras, and to perform real-time tumour-acidosis-guided detection and surgery of occult nodules (< 1 mm3) in mice bearing head-and-neck or breast tumours, significantly lengthening mice survivability. We also show that the pH nanoprobe can be used as a reporter in a fast, quantitative assay to screen for tumour-acidosis inhibitors. The binary delineation of pH achieved by the nanoprobe promises to improve the accuracy of cancer detection, surveillance and therapy.
Carbon nanotube (CNT) aerogels and sponges are macroscopic porous materials with a unique isotropic structure. CNTs make an interconnected 3D scaffold, therefore the resulting aerogels are robust, highly conductive, and flexible, enabling a much broader range of applications than aligned arrays and thin films, especially in energy and environmental areas. A comprehensive overview of the recent progress in isotropic CNT‐based macroscopic structures is provided, including their synthesis methods, structural characteristics, mechanical properties, and deformation mechanism, as well as potential applications in energy and environmental fields. In particular, this study focuses on the CNT sponges developed, which are high‐performance porous materials with many distinct properties such as their versatile deformations and shape recovery. Importantly, the CNT sponges provide a universal platform for designing and manufacturing a variety of hierarchical functional composites by introducing polymers or inorganic guests, thus greatly extend application areas from highly compressible electrodes for supercapacitors and batteries, catalysis, to environmental cleanup. Future research directions and associated challenges in this field are proposed.
Carbon nanotube sponges and aligned arrays are seamlessly integrated into numerous possible configurations such as series, parallel, package, and sandwich complex structures, leading to significantly broadened stress plateau and enhanced energy dissipation.
Flexible
and lightweight high-performance electromagnetic interference
shielding materials with minimal thickness, excellent mechanical properties,
and outstanding reliability are highly desired in the field of fifth-generation
(5G) communication, yet remain extremely challenging to manufacture.
Herein, we prepared an ultrathin densified carbon nanotube (CNT) film
with superior mechanical properties and ultrahigh shielding effectiveness.
Upon complete removal of impurities in pristine CNT film, charge separation
in individual CNTs induced by polar molecules leads to strong CNT–CNT
attraction and film densification, which significantly improve the
electrical conductivity, shielding performance, and mechanical strength.
The tensile strength is up to 822 ± 21 MPa, meanwhile the electrical
conductivity is as high as 902,712 S/m, and the density is only 1.39
g cm–3. Notably, the shielding effectiveness is
over 51 dB with a thickness of merely 1.85 μm in the broad frequency
range of 4–18 GHz, and it reaches to ∼82 dB at 6.36
μm and ∼101 dB at 14.7 μm, respectively. Further,
such CNT film exhibits excellent reliability after an extended period
in strong acid/alkali, high temperature, and high humidity. It demonstrates
the best overall performance among representative shielding materials
by far, representing a critical breakthrough in the preparation of
shielding film toward applications in wearable electronics and 5G
communication.
Flexible supercapacitors, which can sustain large deformations while maintaining normal functions and reliability, are playing an increasingly important role in portable electronics. Here we report the preparation of a three-dimensional α-Fe 2 O 3 /carbon nanotube (CNT@Fe 2 O 3 ) sponge electrode with a porous hierarchical structure, consisting of a compressible, conductive CNT network, coated with a layer of Fe 2 O 3 nanohorns. The specific capacitance of these hybrid sponges has been significantly improved to above 300 F/g, while the equivalent series resistance remains at about 1.5 Ω. The highly deformed CNT@Fe 2 O 3 sponge retains more than 90 % of the original specific capacitance under a compressive strain of 70% (corresponding to a volume reduction of 70%). The hybrid sponge still works stably and sustains similar specific capacitance as initial value even after 1000 compression cycles at a strain of 50%. The outstanding properties of this hybrid sponge make it a highly promising candidate for flexible energy devices.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.